(E)-(4-Styrylphenyl)methanamine

Base Information

Chemical Name:(E)-(4-Styrylphenyl)methanamine
CAS No.:36092-33-8
Molecular Formula:C15H15N
Molecular Weight:209.2863
Hs Code.:
DSSTox Substance ID:DTXSID90570500
Nikkaji Number:J2.247.500B
Wikidata:Q82457976
Mol file:36092-33-8.mol

Synonyms:(E)-(4-Styrylphenyl)methanamine;36092-33-8;SCHEMBL4156175;SCHEMBL11781814;DTXSID90570500;AKOS015967590;1-{4-[(E)-2-Phenylethenyl]phenyl}methanamine

Suppliers and Price of (E)-(4-Styrylphenyl)methanamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 8 raw suppliers

Chemical Property of (E)-(4-Styrylphenyl)methanamine

Chemical Property:

XLogP3:3.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:209.120449483
Heavy Atom Count:16
Complexity:208

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C=CC2=CC=C(C=C2)CN
Isomeric SMILES:C1=CC=C(C=C1)/C=C/C2=CC=C(C=C2)CN

Technology Process of (E)-(4-Styrylphenyl)methanamine

There total 9 articles about (E)-(4-Styrylphenyl)methanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 244059-02-7
4-(phthalimidomethyl)-trans-stilbene

: 36092-33-8
4-[(1E)-2-(phenyl)ethenyl]benzenemethanamine

Guidance literature:: With hydrazine; In ethanol; Heating;
DOI:10.1021/jo0509049

Reference yield:

: 150253-59-1
trans-4-chloromethylstilbene

: 36092-33-8
4-[(1E)-2-(phenyl)ethenyl]benzenemethanamine

Guidance literature:: Multi-step reaction with 2 steps

1: 758.5 mg / dimethylformamide / 120 °C

2: 1.) hydrazine monohydrate, 2.) aq. HCl / 1.) MeOH, reflux, 4 h, 2.) MeOH, reflux, 3 h

With hydrogenchloride; hydrazine hydrate; In N,N-dimethyl-formamide;
DOI:10.1021/jm9811155

Reference yield:

: 2417-72-3
Methyl 4-(bromomethyl)benzoate

: 36092-33-8
4-[(1E)-2-(phenyl)ethenyl]benzenemethanamine

Guidance literature:: Multi-step reaction with 4 steps

1.1: PPh₃ / toluene / Heating

1.2: Bu₄NI; K₂CO₃ / CH₂Cl₂

1.3: 85 percent / I₂ / Irradiation

2.1: 90 percent / LAH / tetrahydrofuran

3.1: 75 percent / PPh₃; DIAD

4.1: 90 percent / hydrazine / ethanol / Heating

With lithium aluminium tetrahydride; di-isopropyl azodicarboxylate; triphenylphosphine; hydrazine; In tetrahydrofuran; ethanol; toluene; 3.1: Mitsunobu reaction;
DOI:10.1021/jo0509049