Phenyl 3,6-diazido-3,6-dideoxy-2,4-bis-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside

Base Information

Chemical Name:Phenyl 3,6-diazido-3,6-dideoxy-2,4-bis-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside
CAS No.:688744-61-8
Molecular Formula:C26H26N6O3S
Molecular Weight:0
Hs Code.:

Synonyms:Phenyl 3,6-diazido-3,6-dideoxy-2,4-bis-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside

Suppliers and Price of Phenyl 3,6-diazido-3,6-dideoxy-2,4-bis-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Phenyl 3,6-diazido-3,6-dideoxy-2,4-bis-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside

Chemical Property:

Purity/Quality:: 95% ^*data from raw suppliers

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Technology Process of Phenyl 3,6-diazido-3,6-dideoxy-2,4-bis-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside

There total 4 articles about Phenyl 3,6-diazido-3,6-dideoxy-2,4-bis-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-39-0
benzyl bromide

: (2R,3S,4S,5R,6S)-4-Azido-2-azidomethyl-6-phenylsulfanyl-tetrahydro-pyran-3,5-diol

: 688744-61-8
phenyl 3,6-diazido-2,4-di-O-benzyl-3,6-dideoxy-1-thio-β-D-glucopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃;
DOI:10.1002/ejoc.200400020

Reference yield:

: 139631-37-1
3-azido-1,3-dideoxy-1-(phenylsulfenyl)-2,4,6-tri-O-acetyl-β-D-gluco-pyranose

: 688744-61-8
phenyl 3,6-diazido-2,4-di-O-benzyl-3,6-dideoxy-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: potassium tert-butoxide / methanol / 1 h

2: 550 mg / pyridine / 20 °C

3: sodium azide / dimethylformamide / 70 °C

4: 566 mg / NaH / dimethylformamide / 0 °C

With pyridine; sodium azide; potassium tert-butylate; sodium hydride; In methanol; N,N-dimethyl-formamide;
DOI:10.1002/ejoc.200400020

Reference yield:

: 205676-46-6
phenyl 3-azido-3-deoxy-1-thio-β-D-glucopyranoside

: 688744-61-8
phenyl 3,6-diazido-2,4-di-O-benzyl-3,6-dideoxy-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 550 mg / pyridine / 20 °C

2: sodium azide / dimethylformamide / 70 °C

3: 566 mg / NaH / dimethylformamide / 0 °C

With pyridine; sodium azide; sodium hydride; In N,N-dimethyl-formamide;
DOI:10.1002/ejoc.200400020