1-Bromo-4-(bromomethyl)-2-chlorobenzene

Base Information

Chemical Name:1-Bromo-4-(bromomethyl)-2-chlorobenzene
CAS No.:68120-44-5
Molecular Formula:C7H5Br2Cl
Molecular Weight:284.378
Hs Code.:2903999090
European Community (EC) Number:896-769-2
DSSTox Substance ID:DTXSID80513648
Wikidata:Q82373563

Synonyms:4-Bromo-3-chlorobenzyl bromide;68120-44-5;1-BROMO-4-(BROMOMETHYL)-2-CHLOROBENZENE;MFCD08059101;3-Chloro-4-bromobenzyl bromide;4-Bromo-3-chlorobenzylbromide;SCHEMBL507688;4-Bromo-3-chloro-benzyl bromide;DTXSID80513648;XCJXYTFYKPVYMK-UHFFFAOYSA-N;AKOS005259828;AS-40423;FT-0684425;1-BROMO-4-BROMOMETHYL-2-CHLORO-BENZENE;EN300-1897069;1-Bromo-4-(bromomethyl)-2-chlorobenzene, AldrichCPR

Suppliers and Price of 1-Bromo-4-(bromomethyl)-2-chlorobenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-Bromo-3-chlorobenzylbromide
250mg
$ 55.00

Sigma-Aldrich
1-Bromo-4-(bromomethyl)-2-chlorobenzene Aldrich
1g
$ 57.00

Oakwood
4-Bromo-3-chlorobenzylbromide 98%
25g
$ 284.00

Matrix Scientific
1-Bromo-4-(bromomethyl)-2-chlorobenzene 95%
5g
$ 87.00

Matrix Scientific
1-Bromo-4-(bromomethyl)-2-chlorobenzene 95%
1g
$ 28.00

Crysdot
4-Bromo-3-chlorobenzylbromide 95+%
5g
$ 195.00

Crysdot
4-Bromo-3-chlorobenzylbromide 95+%
25g
$ 430.00

American Custom Chemicals Corporation
4-BROMO-3-CHLOROBENZYL BROMIDE 95.00%
5MG
$ 495.46

Alichem
4-Bromo-3-chlorobenzylbromide
1g
$ 1490.00

Alichem
4-Bromo-3-chlorobenzylbromide
500mg
$ 831.30

Total 15 raw suppliers

Chemical Property of 1-Bromo-4-(bromomethyl)-2-chlorobenzene

Chemical Property:

PSA：0.00000
LogP:3.99740
Storage Temp.:2-8°C
XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:283.84260
Heavy Atom Count:10
Complexity:108

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Bromo-3-chlorobenzylbromide ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:T
Statements: 25
Safety Statements: 45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=C(C=C1CBr)Cl)Br

Technology Process of 1-Bromo-4-(bromomethyl)-2-chlorobenzene

There total 4 articles about 1-Bromo-4-(bromomethyl)-2-chlorobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 120077-68-1
(4-bromo-3-chlorophenyl)methanol

: 68120-44-5
1-bromo-4-(bromomethyl)-2-chloro-benzene

Guidance literature:: With carbon tetrabromide; triphenylphosphine; In dichloromethane; at 0 - 20 ℃; for 18h; Inert atmosphere;
DOI:10.1021/acs.jmedchem.7b00210

Reference yield: 94.0%

: 6627-51-6
1-bromo-2-chloro-4-methylbenzene

: 68120-44-5
1-bromo-4-(bromomethyl)-2-chloro-benzene

Guidance literature:: With N-Bromosuccinimide; dibenzoyl peroxide; In tetrachloromethane; for 18h; Reflux;

Reference yield:

: 25118-59-6
4-bromo-3-chlorobenzoic acid

: 68120-44-5
1-bromo-4-(bromomethyl)-2-chloro-benzene

Guidance literature:: Multi-step reaction with 3 steps

1: sulfuric acid / 4 h / Inert atmosphere; Reflux

2: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / -15 - 0 °C / Inert atmosphere

3: triphenylphosphine; N-Bromosuccinimide / dichloromethane / 0.5 h / -10 - 20 °C / Inert atmosphere

With N-Bromosuccinimide; lithium aluminium tetrahydride; sulfuric acid; triphenylphosphine; In tetrahydrofuran; dichloromethane;