6,6-Dibromobicyclo[3.1.0]hexane

Base Information

• Chemical Name: 6,6-Dibromobicyclo[3.1.0]hexane
• CAS No.: 2568-36-7
• Molecular Formula: C6H8Br2
• Molecular Weight: 239.938
• DSSTox Substance ID: DTXSID00456669
• Nikkaji Number: J80.517C
• Mol file: 2568-36-7.mol

Synonyms:6,6-dibromobicyclo[3.1.0]hexane;2568-36-7;DTXSID00456669;6,6-dibromobicyclo[3.1.0]-hexane

Chemical Property of 6,6-Dibromobicyclo[3.1.0]hexane

Chemical Property:

• PSA: 0.00000
• LogP: 2.90240
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 239.89723
• Heavy Atom Count: 8
• Complexity: 108

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC2C(C1)C2(Br)Br

Technology Process of 6,6-Dibromobicyclo[3.1.0]hexane

There total 5 articles about 6,6-Dibromobicyclo[3.1.0]hexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

Bromoform (75-25-2) + cyclopentene (142-29-0) → 6,6-dibromobicylo[3.1.0]hexane (2568-36-7)

Guidance literature:

With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; In benzene; at 0 - 18 ℃; for 18h;

DOI:10.1021/ol062020x

Reference yield:

cyclopentene (142-29-0) + 1,1-dibromomethane (74-95-3) → 6,6-dibromobicylo[3.1.0]hexane (2568-36-7)

Guidance literature:

at 0 ℃;

DOI:10.1021/ja01601a073

Reference yield:

Bromoform (75-25-2) + cyclopentene (142-29-0) → 6,6-dibromobicyclo<3.1.0>hexane (2568-36-7) + (1R,5R)-6,6-Dibromo-bicyclo[3.1.0]hexane (2568-36-7)

Guidance literature:

With potassium tert-butylate; In hexane; for 2h; Rate constant;

upstream raw materials:

Bromoform

cyclopentene

1,1-dibromomethane

Downstream raw materials:

2-bromocyclohex-2-en-1-ol

3-bromo-1-(methylthio)benzene

2-bromo-1-(methylsulfanyl)benzene

1,6-dibromocyclohex-1-ene