6-Trimethylsilylmethyl-3,4,4a,5,8,8a-hexahydro-1(2H)-naphthalenone

Base Information

Chemical Name:6-Trimethylsilylmethyl-3,4,4a,5,8,8a-hexahydro-1(2H)-naphthalenone
CAS No.:82096-10-4
Molecular Formula:C₁₄H₂₄OSi
Molecular Weight:236.429
Hs Code.:
DSSTox Substance ID:DTXSID00701525
Nikkaji Number:J46.980G
Mol file:82096-10-4.mol

Synonyms:82096-10-4;6-Trimethylsilylmethyl-3,4,4a,5,8,8a-hexahydro-1(2H)-naphthalenone;DTXSID00701525;6-[(Trimethylsilyl)methyl]-3,4,4a,5,8,8a-hexahydronaphthalen-1(2H)-one

Suppliers and Price of 6-Trimethylsilylmethyl-3,4,4a,5,8,8a-hexahydro-1(2H)-naphthalenone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 6-Trimethylsilylmethyl-3,4,4a,5,8,8a-hexahydro-1(2H)-naphthalenone

Chemical Property:

PSA：17.07000
LogP:4.03020
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:236.159641919
Heavy Atom Count:16
Complexity:311

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)CC1=CCC2C(C1)CCCC2=O

Technology Process of 6-Trimethylsilylmethyl-3,4,4a,5,8,8a-hexahydro-1(2H)-naphthalenone

There total 2 articles about 6-Trimethylsilylmethyl-3,4,4a,5,8,8a-hexahydro-1(2H)-naphthalenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 930-68-7
cyclohexenone

: 70901-64-3
trimethyl(2-methylenebut-3-enyl)silane

: 82096-10-4
6-Trimethylsilanylmethyl-3,4,4a,5,8,8a-hexahydro-2H-naphthalen-1-one

Guidance literature:: aluminium trichloride; In benzene; at 80 ℃; for 2h; without cat. at 135 deg C, 20 h;
DOI:10.1016/S0040-4039(00)86886-0

Reference yield:

: 930-68-7
cyclohexenone

: 70901-64-3
trimethyl(2-methylenebut-3-enyl)silane

: 82096-10-4
6-Trimethylsilanylmethyl-3,4,4a,5,8,8a-hexahydro-2H-naphthalen-1-one

: 82096-13-7
7-Trimethylsilanylmethyl-3,4,4a,5,8,8a-hexahydro-2H-naphthalen-1-one

Guidance literature:: With aluminium trichloride; In benzene; at 80 ℃; for 2h; Product distribution; Aluminium trichloride catalysis gave much higher regioselectivity.;
DOI:10.1016/S0040-4020(01)88587-2