Bicycloocta-2.5-dien-2-carbonsaeureaethylester

Base Information

• Chemical Name: Bicycloocta-2.5-dien-2-carbonsaeureaethylester
• CAS No.: 39863-21-3
• Molecular Formula: C11H14O2
• Molecular Weight: 178.23
• Mol file: 39863-21-3.mol

Synonyms:Bicycloocta-2.5-dien-2-carbonsaeureaethylester;Ethyl bicyclo[2.2.2]octa-2,5-diene-2-carboxylate

Chemical Property of Bicycloocta-2.5-dien-2-carbonsaeureaethylester

Chemical Property:

• PSA: 26.30000
• LogP: 2.07190
• Storage Temp.: 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

Ethylbicyclo[2.2.2]octa-2,5-diene-2-carboxylate 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bicycloocta-2.5-dien-2-carbonsaeureaethylester

There total 6 articles about Bicycloocta-2.5-dien-2-carbonsaeureaethylester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

3,3,3-triethoxypropyne (42217-00-5) + cyclohexa-1,3-diene (1165952-91-9) → 2-Carboethoxy<2.2.2>bicyclooctadien-2.5 (39863-21-3)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -78 - -15 ℃; for 1.6h;

DOI:10.1016/0040-4039(88)85175-X

Reference yield: 28.0%

trimethylsilyl cyanide (7677-24-9) + 3,3,3-triethoxypropyne (42217-00-5) + cyclohexa-1,3-diene (1165952-91-9) → 2-Carboethoxy<2.2.2>bicyclooctadien-2.5 (39863-21-3) + Bicyclo[2.2.2]octa-2,5-dien-2-yl-diethoxy-acetonitrile (118451-57-3)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; at -78 ℃; for 0.416667h;

DOI:10.1016/0040-4039(88)85175-X

Reference yield:

3-Benzenesulfinyl-bicyclo[2.2.2]oct-5-ene-2-carboxylic acid ethyl ester → 2-Carboethoxy<2.2.2>bicyclooctadien-2.5 (39863-21-3)

Guidance literature:

at 50 ℃;

DOI:10.1021/ja00801a058

upstream raw materials:

5--bicyclo<2.2.2>octen-(2)

2-(Phenylthio)-bicyclo-<2.2.2>-oct-5-en-2-carbonsaeureethylester

trimethylsilyl cyanide

3,3,3-triethoxypropyne