10-Hydroxyundecanoic acid methyl ester

Base Information

• Chemical Name: 10-Hydroxyundecanoic acid methyl ester
• CAS No.: 54704-39-1
• Molecular Formula: C₁₂H₂₄O₃
• Molecular Weight: 216.321
• Mol file: 54704-39-1.mol

Synonyms:(+/-)-10-Hydroxyundecansaeure-methylester;Undecanoic acid, 10-hydroxy-, methyl ester

Chemical Property of 10-Hydroxyundecanoic acid methyl ester

Chemical Property:

• Boiling Point: 127-130 °C(Press: 2 Torr)
• PKA: 15.26±0.20(Predicted)
• Density: 0.948±0.06 g/cm3(Predicted)

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10-Hydroxyundecanoic acid methyl ester

There total 14 articles about 10-Hydroxyundecanoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

methyl 10-oxoundecanoate (18993-09-4) → (+/-)-10-Hydroxyundecansaeure-methylester (54704-39-1,35005-54-0)

Guidance literature:

With methanol; sodium tetrahydroborate; In dichloromethane; at 20 ℃;

DOI:10.1002/anie.201804368

Reference yield: 44.0%

methyl 11-bromo-10-hydroxyundecanoate (34574-67-9) → Methyl 10-undecenoate (111-81-9) + (+/-)-10-Hydroxyundecansaeure-methylester (54704-39-1,35005-54-0) + methyl 10-oxoundecanoate (18993-09-4) + methyl 8-undecenote (100288-72-0)

Guidance literature:

With chlorotris(triphenylphosphine)cobalt(I); In benzene; at 60 ℃; for 7.5h; Yield given;

Reference yield: 44.0%

methyl 11-bromo-10-hydroxyundecanoate (34574-67-9) → Methyl 10-undecenoate (111-81-9) + (+/-)-10-Hydroxyundecansaeure-methylester (54704-39-1,35005-54-0) + methyl 10-oxoundecanoate (18993-09-4) + methyl 8-undecenoate (64749-27-5)

Guidance literature:

With chlorotris(triphenylphosphine)cobalt(I); for 6h; Yield given. Further byproducts given; Ambient temperature;

DOI:10.1016/S0040-4039(00)87973-3

upstream raw materials:

methanol

10-hydroxyundecanoic acid

Methyl 10-undecenoate

methyl 11-bromo-10-hydroxyundecanoate

Downstream raw materials:

1,1-Diphenyl-10-hydroxyundec-1-en

methyl 10-(tosyloxy)undecanoate

(R)-11-Methyl-oxacycloundecan-2-one

methyl (R)-10-hydroxyundecanoate