D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-6-S-phenyl-6-thio-, diacetate

Base Information

Chemical Name:D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-6-S-phenyl-6-thio-, diacetate
CAS No.:88111-84-6
Molecular Formula:C₁₆H₁₈O₅S
Molecular Weight:322.382
Hs Code.:

Synonyms:D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-6-S-phenyl-6-thio-, diacetate

Suppliers and Price of D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-6-S-phenyl-6-thio-, diacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 3 raw suppliers

Chemical Property of D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-6-S-phenyl-6-thio-, diacetate

Chemical Property:

Purity/Quality:

Safty Information:

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Hazard Codes:

MSDS Files:

Useful:

Technology Process of D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-6-S-phenyl-6-thio-, diacetate

There total 3 articles about D-arabino-Hex-1-enitol, 1,5-anhydro-2-deoxy-6-S-phenyl-6-thio-, diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: Acetic acid (E)-(1S,2R)-2-acetoxy-1-((R)-1-acetoxy-2-oxo-ethyl)-4-phenylsulfanyl-but-3-enyl ester

: 88111-84-6
3,4-di-O-acetyl-1,5-anhydro-2-deoxy-6-S-phenyl-6-thio-D-arabino-hex-1-enitol

: 88111-85-7,88196-02-5
(6S)-3,4,6-tri-O-acetyl-1,5-anhydro-2-deoxy-6-phenylthio-D-arabino-hex-1-enitol

: 88196-01-4
(1R,5S)-6-exo,7-endo,8-exo-triacetoxy-N-methyl-4-exo-phenylthio-3-oxa-2-azabicyclo<3.3.0>octane

: 88111-83-5
(1R,5S)-6-exo,7-endo,8-exo-triacetoxy-N-methyl-4-endo-phenylthio-3-oxa-2-azabicyclo<3.3.0>octane

Guidance literature:: With pyridine; N-methylhydroxyamine hydrochloride; In ethanol; at 50 ℃; for 0.5h; Further byproducts given;

Reference yield: 38.0%

: 4229-44-1
N-methylhydroxyamine hydrochloride

: Acetic acid (E)-(1S,2R)-2-acetoxy-1-((R)-1-acetoxy-2-oxo-ethyl)-4-phenylsulfanyl-but-3-enyl ester

: 88111-84-6
3,4-di-O-acetyl-1,5-anhydro-2-deoxy-6-S-phenyl-6-thio-D-arabino-hex-1-enitol

: 88111-85-7,88196-02-5
(6S)-3,4,6-tri-O-acetyl-1,5-anhydro-2-deoxy-6-phenylthio-D-arabino-hex-1-enitol

: 88196-01-4
(1R,5S)-6-exo,7-endo,8-exo-triacetoxy-N-methyl-4-exo-phenylthio-3-oxa-2-azabicyclo<3.3.0>octane

: 88111-83-5
(1R,5S)-6-exo,7-endo,8-exo-triacetoxy-N-methyl-4-endo-phenylthio-3-oxa-2-azabicyclo<3.3.0>octane

Guidance literature:: With pyridine; In ethanol; at 50 ℃; for 0.5h; Further byproducts given;

Reference yield:

: 74774-11-1
(6R)-2,3,4,-tri-O-acetyl-1,6-anhydro-6-phenylthio-β-D-glucopyranose

: 88111-84-6
3,4-di-O-acetyl-1,5-anhydro-2-deoxy-6-S-phenyl-6-thio-D-arabino-hex-1-enitol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) hydrogen bromide, 2.) zinc, acetic acid, sodium acetate, copper(II) sulphate / 1.) chloroform, acetic anhydride, 20 deg C, 5 h, 2.) water, 2 h

2: pyridine, N-methylhydroxylamine hydrochloride / ethanol / 0.5 h / 50 °C

With pyridine; N-methylhydroxyamine hydrochloride; hydrogen bromide; sodium acetate; copper(II) sulfate; acetic acid; zinc; In ethanol;