(+/-)-1-Methoxy-4-(trans-2-(trifluoromethyl)cyclopropyl)benzene

Base Information

Chemical Name:(+/-)-1-Methoxy-4-(trans-2-(trifluoromethyl)cyclopropyl)benzene
CAS No.:900779-69-3
Molecular Formula:C₁₁H₁₁F₃O
Molecular Weight:216.203
Hs Code.:2909309090
Mol file:900779-69-3.mol

Synonyms:(+/-)-1-Methoxy-4-(trans-2-(trifluoromethyl)cyclopropyl)benzene

Suppliers and Price of (+/-)-1-Methoxy-4-(trans-2-(trifluoromethyl)cyclopropyl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of (+/-)-1-Methoxy-4-(trans-2-(trifluoromethyl)cyclopropyl)benzene

Chemical Property:

PSA：9.23000
LogP:3.36100

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (+/-)-1-Methoxy-4-(trans-2-(trifluoromethyl)cyclopropyl)benzene

There total 24 articles about (+/-)-1-Methoxy-4-(trans-2-(trifluoromethyl)cyclopropyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 637-69-4,24936-44-5
4-Methoxystyrene

: 371-67-5
2,2,2-trifluorodiazoethane

: 900779-69-3
(-)-1-methoxy-4-(1R,2R)-(2-(trifluoromethyl)cyclopropyl)benzene

Guidance literature:: With Ru-pheox; In dichloromethane; at 0 ℃; Reagent/catalyst; Temperature; stereoselective reaction;
DOI:10.1039/c8cc02286k

Reference yield: 95.0%

: 637-69-4,24936-44-5
4-Methoxystyrene

: 373-88-6
2,2,2-trifluroethylamine hydrochloride

: 900779-69-3
(-)-1-methoxy-4-(1R,2R)-(2-(trifluoromethyl)cyclopropyl)benzene

Guidance literature:: With triphenyl-arsane; sulfuric acid; C₂₈H₃₆CoN₂O₄; sodium acetate; sodium chloride; sodium nitrite; In water; at -15 ℃; for 14h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/anie.201004269

Reference yield: 89.0%

: 637-69-4,24936-44-5
4-Methoxystyrene

: 373-88-6
2,2,2-trifluroethylamine hydrochloride

: 900779-69-3
(+/-)-1-methoxy-4-((trans)-2-(trifluoromethyl)cyclopropyl)benzene

Guidance literature:: With dmap; meso-tetraphenylporphyrin iron(III) chloride; sulfuric acid; sodium acetate; sodium nitrite; In water; at 20 ℃; for 14.0167h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.200905573