N-methyl ,ethyl-Morpholinium bis((trifluoromethyl)sulfonyl)imide

Base Information

• Chemical Name: N-methyl ,ethyl-Morpholinium bis((trifluoromethyl)sulfonyl)imide
• CAS No.: 706785-83-3
• Molecular Formula: C9H16F6N2O5S2
• Molecular Weight: 410.35
• Mol file: 706785-83-3.mol

Synonyms:N-methyl ,ethyl-Morpholinium bis((trifluoromethyl)sulfonyl)imide

Chemical Property of N-methyl ,ethyl-Morpholinium bis((trifluoromethyl)sulfonyl)imide

Chemical Property:

• Melting Point: 29.2 °C
• PSA: 94.27000
• Density: 1.514 g/cm3
• LogP: 3.66280

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-methyl ,ethyl-Morpholinium bis((trifluoromethyl)sulfonyl)imide

There total 3 articles about N-methyl ,ethyl-Morpholinium bis((trifluoromethyl)sulfonyl)imide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

N-ethylmorpholine; (100-74-3) + N-methyl bis[(trifluoromethyl)sulfonyl]imide (537031-78-0) → N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide salt (706785-83-3)

Guidance literature:

In chloroform; at 70 ℃; for 10h; Inert atmosphere;

Reference yield: 80.0%

bis(trifluoromethane)sulfonimide lithium (90076-65-6) + N-ethyl-N-methylmorpholinium bromide (65756-41-4) → N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide salt (706785-83-3)

Guidance literature:

In dichloromethane; for 24h;

DOI:10.1039/b400198b

Reference yield:

4-methyl-morpholine (109-02-4) → N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide salt (706785-83-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / acetonitrile / 5 h / 60 °C

2: 80 percent / CH₂Cl₂ / 24 h

In dichloromethane; acetonitrile;

DOI:10.1039/b400198b

upstream raw materials:

bis(trifluoromethane)sulfonimide lithium

N-ethyl-N-methylmorpholinium bromide

4-methyl-morpholine

N-ethylmorpholine;

Refernces

• 1、 Marcinkowski, Lukasz,Olszewska, Teresa,Kloskowski, Adam,Warminska, Dorota. "Apparent molar volumes and expansivities of ionic liquids based on N -Alkyl- N -methylmorpholinium cations in acetonitrile". . p. 718 - 725. Retrieved 2014/04/03.