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4-Methylmorpholine

Base Information Edit
  • Chemical Name:4-Methylmorpholine
  • CAS No.:109-02-4
  • Deprecated CAS:205657-43-8
  • Molecular Formula:C5H11NO
  • Molecular Weight:101.148
  • Hs Code.:29349990
  • European Community (EC) Number:203-640-0
  • NSC Number:9382
  • UN Number:2535
  • UNII:11P91ANU5X
  • DSSTox Substance ID:DTXSID9029146
  • Nikkaji Number:J100.752A
  • Wikipedia:N-Methylmorpholine
  • Wikidata:Q2542075
  • ChEMBL ID:CHEMBL2448839
  • Mol file:109-02-4.mol
4-Methylmorpholine

Synonyms:4-methylmorpholine;4-methylmorpholine hydrobromide;4-methylmorpholine hydrochloride;4-methylmorpholine sulfite (1:1);N-methylmorpholine

Suppliers and Price of 4-Methylmorpholine
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • TRC
  • 4-Methylmorpholine
  • 100ml
  • $ 110.00
  • TCI Chemical
  • 4-Methylmorpholine >99.0%(GC)
  • 25mL
  • $ 17.00
  • TCI Chemical
  • 4-Methylmorpholine >99.0%(GC)
  • 500mL
  • $ 40.00
  • SynQuest Laboratories
  • 4-Methylmorpholine 98.5%
  • 500 mL
  • $ 80.00
  • SynQuest Laboratories
  • 4-Methylmorpholine 98.5%
  • 100 mL
  • $ 18.00
  • Sigma-Aldrich
  • 4-Methylmorpholine 4-Methylmorpholine for synthesis. CAS 109-02-4, pH 10.6 (50?g/l, H?O, 20?°C).
  • 8058949025
  • $ 702.00
  • Sigma-Aldrich
  • 4-Methylmorpholine for synthesis
  • 25 kg
  • $ 672.47
  • Sigma-Aldrich
  • 4-Methylmorpholine BioXtra, suitable for protein sequencing, ≥99.5% (GC)
  • 100ml
  • $ 144.00
  • Sigma-Aldrich
  • 4-Methylmorpholine BioXtra, suitable for protein sequencing, ≥99.5% (GC)
  • 500ml
  • $ 567.00
  • Sigma-Aldrich
  • 4-Methylmorpholine for synthesis. CAS 109-02-4, pH 10.6 (50 g/l, H O, 20 °C)., for synthesis
  • 8058940005
  • $ 19.30
Total 113 raw suppliers
Chemical Property of 4-Methylmorpholine Edit
Chemical Property:
  • Appearance/Colour:clear liquid 
  • Vapor Pressure:18 mm Hg ( 20 °C) 
  • Melting Point:-66 °C(lit.) 
  • Refractive Index:n20/D 1.435(lit.)  
  • Boiling Point:114.1 °C at 760 mmHg 
  • PKA:7.38(at 25℃) 
  • Flash Point:23.9 °C 
  • PSA:12.47000 
  • Density:0.931 g/cm3 
  • LogP:-0.11370 
  • Storage Temp.:Store at RT. 
  • Water Solubility.:>500 g/L (20 ºC) 
  • XLogP3:-0.3
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:2
  • Rotatable Bond Count:0
  • Exact Mass:101.084063974
  • Heavy Atom Count:7
  • Complexity:50
  • Transport DOT Label:Flammable Liquid Corrosive
Purity/Quality:

99% *data from raw suppliers

4-Methylmorpholine *data from reagent suppliers

Safty Information:
  • Pictogram(s): CorrosiveC,Flammable
  • Hazard Codes:F,C 
  • Statements: 11-20/21/22-34-10-22 
  • Safety Statements: 16-26-36/37/39-45-25 
MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:
  • Chemical Classes:Nitrogen Compounds -> Morpholines
  • Canonical SMILES:CN1CCOCC1
  • Uses 4-Methylmorpholine is an excellent solvent, emulsifier, corrosion inhibitor, Catalyst in polyurethane foamsextraction solvent, stabilizing agent for chlorinated hydrocarbons, and also can be used as pesticide intermediates. 4-Methylmorpholine is widely used in the synthesis of pesticide compounds such as insecticide, fungicide, plant growth regulator, etc. It is also used in the synthesis of fine chemicals such as surfactant, lubricant coolant, metal antirust agent, fiber treatment agent, etc. 4-Methylmorpholine is used as a solvent for dyes, resins, waxes and pharmaceuticals. It acts as a crosslinker in the preparation of polyurethane foams, elastomers and adhesives. It is used as a precursor to prepare N-methylmorpholine N-oxide and morpholinium cation based ionic liquids. It is utilized as corrosion inhibitors and anti-scaling agents in industries.
Technology Process of 4-Methylmorpholine

There total 88 articles about 4-Methylmorpholine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With oxalic acid; at 100 - 120 ℃;
DOI:10.1081/SCC-120002131
Guidance literature:
With carbon dioxide; water; iron; at 100 ℃; for 10h; under 15001.5 Torr; chemoselective reaction; Autoclave; Green chemistry;
DOI:10.1039/c3gc40243f
Guidance literature:
N-Methyldiethanolamine; With sulfuric acid; at 60 - 170 ℃; for 7.5h;
at 60 - 70 ℃; for 0.5h; Temperature; Reagent/catalyst; Time;
Refernces Edit
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