3-Methoxy-4-(methoxycarbonyl)benzoic acid

Base Information

Chemical Name:3-Methoxy-4-(methoxycarbonyl)benzoic acid
CAS No.:162046-51-7
Molecular Formula:C₁₀H₁₀O₅
Molecular Weight:210.186
Hs Code.:
European Community (EC) Number:965-149-4
Mol file:162046-51-7.mol

Synonyms:3-methoxy-4-(methoxycarbonyl)benzoic acid;162046-51-7;2-Methoxy-terephthalic acid 1-methyl ester;3-methoxy-4-methoxycarbonylbenzoic acid;SCHEMBL7019824;MAIDVTUHEDEKMF-UHFFFAOYSA-N;MFCD24039315;SB34056;3-methoxy-4-(methoxycarbonyl)benzoicacid;CS-0341581;FT-0758182;EN300-379337;1-Methoxycarbonyl-2-methoxybenzene 4-carboxylic acid

Suppliers and Price of 3-Methoxy-4-(methoxycarbonyl)benzoic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of 3-Methoxy-4-(methoxycarbonyl)benzoic acid

Chemical Property:

XLogP3:1.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:4
Exact Mass:210.05282342
Heavy Atom Count:15
Complexity:250

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=C(C=CC(=C1)C(=O)O)C(=O)OC

Technology Process of 3-Methoxy-4-(methoxycarbonyl)benzoic acid

There total 4 articles about 3-Methoxy-4-(methoxycarbonyl)benzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 55204-14-3
methyl 4-formyl-2-methoxybenzoate

: 162046-51-7
1-Methoxycarbonyl-2-methoxybenzene 4-carboxylic acid

Guidance literature:: With selenium(IV) oxide; dihydrogen peroxide; In tert-butyl alcohol; for 18h; Yield given; Ambient temperature;
DOI:10.1080/00397919508015893

Reference yield:

: 81245-24-1
methyl 4-methyl-2-methoxybenzoate

: 162046-51-7
1-Methoxycarbonyl-2-methoxybenzene 4-carboxylic acid

Guidance literature:: Multi-step reaction with 3 steps

1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / 18 h / Reflux

2: nitromethane; sodium methylate / methanol / Inert atmosphere; Reflux

3: aminosulfonic acid; sodium chlorite / water; acetone / 0 - 20 °C

With sodium chlorite; N-Bromosuccinimide; nitromethane; 2,2'-azobis(isobutyronitrile); aminosulfonic acid; sodium methylate; In methanol; tetrachloromethane; water; acetone;

Reference yield:

: 50-85-1
2-hydroxy-p-toluic acid

: 162046-51-7
1-Methoxycarbonyl-2-methoxybenzene 4-carboxylic acid

Guidance literature:: Multi-step reaction with 4 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 1 h / 60 °C

1.2: 18 h / 60 °C

2.1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / 18 h / Reflux

3.1: nitromethane; sodium methylate / methanol / Inert atmosphere; Reflux

4.1: aminosulfonic acid; sodium chlorite / water; acetone / 0 - 20 °C

With sodium chlorite; N-Bromosuccinimide; nitromethane; 2,2'-azobis(isobutyronitrile); aminosulfonic acid; sodium methylate; potassium carbonate; In methanol; tetrachloromethane; water; N,N-dimethyl-formamide; acetone;