5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III)chloride

Base Information

• Chemical Name: 5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III)chloride
• CAS No.: 62769-24-8
• Molecular Formula: C₄₈H₃₆ClMnN₄O₄
• Molecular Weight: 823.229
• Mol file: 62769-24-8.mol

Synonyms:5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III)chloride;Chlorotetra(4-chlorophenyl)porphinatomanganese

Chemical Property of 5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III)chloride

Chemical Property:

• PSA: 52.80000
• LogP: 7.16170
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

99%+, ^*data from raw suppliers

5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III)chloride 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III)chloride

There total 3 articles about 5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphinemanganese(III)chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.5%

manganese(II) chloride tetrahydrate + 5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin (22112-78-3) → 5,10,15,20-tetra(4-methoxyphenyl) porphyrinato manganese chloride (62769-24-8)

Guidance literature:

In N,N-dimethyl-formamide; for 0.5h; Reflux;

DOI:10.1021/op060056z

Reference yield: 91.0%

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin (22112-78-3) → 5,10,15,20-tetra(4-methoxyphenyl) porphyrinato manganese chloride (62769-24-8)

Guidance literature:

With [Mn(III)(acac)2Cl]; acetic anhydride; acetic acid; for 4h; Reflux;

DOI:10.1080/00958972.2011.632412

Reference yield:

hydroxo(tetrakis(p-methoxyphenyl)porphinato)manganese(III) → 5,10,15,20-tetra(4-methoxyphenyl) porphyrinato manganese chloride (62769-24-8)

Guidance literature:

With hydrogenchloride; In dichloromethane; stirred with 1 M aq. HCl; heptane was added, vac.-dried at 100°C;

upstream raw materials:

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin

Downstream raw materials:

{Mn(C₅H₂N(C₆H₄OCH₃))4(C₄H₈O)2}⁽¹⁺⁾

5,10,15,20-tetrakis(p-methoxyphenyl)porphinatomanganese(III) fluoride

[Mn(NO)(piperidine)(C₂₀H₈N₄(p-MeOC₆H₄)4)]

Refernces

• 1、 Wang, Lanzhi,She, Yuanbin,Zhong, Rugang,Ji, Hongbing,Zhang, Yanhui,Song, Xufeng. "A green process for oxidation of p-nitrotoluene catalyzed by metalloporphyrins under mild conditions". . p. 757 - 761. Retrieved 2012/12/22.