(4,4'‐didodecyl‐2,2'‐ bithiophene‐5,5'‐ diyl)bis(triMethylstann ane)

Base Information

Chemical Name:(4,4'‐didodecyl‐2,2'‐ bithiophene‐5,5'‐ diyl)bis(triMethylstann ane)
CAS No.:1007347-63-8
Molecular Formula:C38H70S2Sn2
Molecular Weight:828.51
Hs Code.:
Mol file:1007347-63-8.mol

Synonyms:(4,4'‐didodecyl‐2,2'‐ bithiophene‐5,5'‐ diyl)bis(triMethylstann ane);1,1'-(4,4'-Didodecyl[2,2'-bithiophene]-5,5'-diyl)bis[1,1,1-trimethylstannane]

Suppliers and Price of (4,4'‐didodecyl‐2,2'‐ bithiophene‐5,5'‐ diyl)bis(triMethylstann ane)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 21 raw suppliers

Chemical Property of (4,4'‐didodecyl‐2,2'‐ bithiophene‐5,5'‐ diyl)bis(triMethylstann ane)

Chemical Property:

Boiling Point:689.3±65.0 °C(Predicted)
PSA：56.48000
LogP:13.49380

Purity/Quality:: 99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (4,4'‐didodecyl‐2,2'‐ bithiophene‐5,5'‐ diyl)bis(triMethylstann ane)

There total 4 articles about (4,4'‐didodecyl‐2,2'‐ bithiophene‐5,5'‐ diyl)bis(triMethylstann ane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1066-45-1
trimethyltin(IV)chloride

: 5,5′-dibromo-4,4′-didodecyl-2,2′-bithiophene

: 1007347-63-8
5,5'-bis(trimethylstannyl)-4,4'-bis(dodecyl)-2,2'-bithiophene

Guidance literature:: 5,5′-dibromo-4,4′-didodecyl-2,2′-bithiophene; With n-butyllithium; In hexane; cyclohexane; at 0 - 60 ℃;

trimethyltin(IV)chloride; In hexane; at 0 - 20 ℃;
DOI:10.1002/pola.26456

Reference yield: 80.0%

: 345633-76-3
4,4’-bis(dodecyl)-2,2’-bithiophene

: 1066-45-1
trimethyltin(IV)chloride

: 1007347-63-8
5,5'-bis(trimethylstannyl)-4,4'-bis(dodecyl)-2,2'-bithiophene

Guidance literature:: With C₄H₉Li; In tetrahydrofuran; treatment of dithiophene deriv. with butyllithium and then with tin compd. in THF at -78°C with warming to room temp.; recrystn. (hexane) at -78°C, NMR;
DOI:10.1021/ja107678m

Reference yield:

: 104934-52-3,104934-53-4
3-dodecylthiophene

: 1007347-63-8
5,5'-bis(trimethylstannyl)-4,4'-bis(dodecyl)-2,2'-bithiophene

Guidance literature:: Multi-step reaction with 2 steps

1: n-butyllithium; copper dichloride

2: 2,2,6,6-tetramethylpiperidinyl-lithium

With n-butyllithium; 2,2,6,6-tetramethylpiperidinyl-lithium; copper dichloride;
DOI:10.1021/cm3021929