(11bR)-(+)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoroMethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepiniuM broMide, 99% R-MARUOKA CAT P-TB

Base Information

Chemical Name:(11bR)-(+)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoroMethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepiniuM broMide, 99% R-MARUOKA CAT P-TB
CAS No.:1101230-28-7
Molecular Formula:C₂₇H₃₉NP₂
Molecular Weight:439.561
Hs Code.:
Mol file:1101230-28-7.mol

Synonyms:(11bR)-(+)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoroMethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepiniuM broMide, 99% R-MARUOKA CAT P-TB;4,5-Bis-(di-i-propylphosphinoMethyl)acridine, 98+%;4,5-Bis-(di-i-propylphosphinomethyl)acridine

Suppliers and Price of (11bR)-(+)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoroMethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepiniuM broMide, 99% R-MARUOKA CAT P-TB

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
(11bR)-(+)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide, 99% R-MARUOKA CAT P-TB
250mg
$ 933.00

Strem Chemicals
4,5-Bis-(di-i-propylphosphinomethyl)acridine, 98+%
250mg
$ 440.00

Strem Chemicals
(11bS)-(-)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide, 99% S-MARUOKA CAT P-TB
250mg
$ 440.00

Strem Chemicals
(11bR)-(+)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide, 99% R-MARUOKA CAT P-TB
50mg
$ 233.00

Strem Chemicals
(11bS)-(-)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide, 99% S-MARUOKA CAT P-TB
50mg
$ 233.00

Strem Chemicals
4,5-Bis-(di-i-propylphosphinomethyl)acridine, 98+%
50mg
$ 110.00

Total 4 raw suppliers

Chemical Property of (11bR)-(+)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoroMethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepiniuM broMide, 99% R-MARUOKA CAT P-TB

Chemical Property:

Boiling Point:565.4±40.0 °C(Predicted)
PKA:5.39±0.10(Predicted)
PSA：40.07000
LogP:8.98540
Sensitive.:air sensitive

Purity/Quality:

97% ^*data from raw suppliers

(11bR)-(+)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepinium bromide, 99% R-MARUOKA CAT P-TB ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses (11bR)-(+)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoroMethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepiniuM broMide, 99% R-MARUOKA CAT P-TB is used to make Milstein Acridine Catalyst.

Technology Process of (11bR)-(+)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoroMethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepiniuM broMide, 99% R-MARUOKA CAT P-TB

There total 1 articles about (11bR)-(+)-4,4-Di-t-butyl-2,6-bis[3,5-bis(trifluoroMethyl)phenyl]-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphepiniuM broMide, 99% R-MARUOKA CAT P-TB which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 20491-53-6
di-isopropylphosphine

: 643742-28-3
4,5-bis-bromomethylacridine

: 1101230-28-7
4,5-bis(di-iso-propylphosphinomethyl)acridine

Guidance literature:: di-isopropylphosphine; 4,5-bis-bromomethylacridine; In methanol; at 50 ℃; for 48h; Sealed flask; Inert atmosphere;

With triethylamine; In methanol; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1002/anie.200803229