1-benzyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole

Base Information

Chemical Name:1-benzyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole
CAS No.:439813-83-9
Molecular Formula:C₁₇H₂₂BNO₂
Molecular Weight:283.178
Hs Code.:
DSSTox Substance ID:DTXSID001143378
Nikkaji Number:J3.594.545H

Synonyms:439813-83-9;1-benzyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole;1H-Pyrrole, 1-(phenylmethyl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-;SCHEMBL14857772;ZGHSKJAXSNIWRQ-UHFFFAOYSA-N;DTXSID001143378;MB13125;CS-0370329;FT-0729785;J3.594.545H;1-BENZYL-1H-PYRROL-3-YLBORONIC ACID PINACOL ESTER;1-benzyl-3-(4,4,5,5 -tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole;1-Benzyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-1H-pyrrole;1-(Phenylmethyl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole

Suppliers and Price of 1-benzyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-benzyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:283.1743591
Heavy Atom Count:21
Complexity:350

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=CN(C=C2)CC3=CC=CC=C3

Technology Process of 1-benzyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole

There total 5 articles about 1-benzyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 100-46-9
benzylamine

: 439813-69-1
(1,4-dichloro-2-buten-2-yl)boronic acid pinacol ester

: 439813-83-9
3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-1-(benzyl)-1H-pyrrole

Guidance literature:: benzylamine; (1,4-dichloro-2-buten-2-yl)boronic acid pinacol ester; In chloroform; at 20 ℃;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In toluene; at 20 ℃;
DOI:10.1055/s-2002-25351

Reference yield:

: 2051-97-0
1-benzyl-1H-pyrrole

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1-benzyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrole

: 439813-83-9
3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-1-(benzyl)-1H-pyrrole

Guidance literature:: With 1-(2-borylphenyl)-2,2,6,6-tetramethylpiperidine dimer; In chloroform; at 80 ℃; for 16h; Overall yield = 90 %;
DOI:10.1126/science.aab3591

Reference yield:

: 18159-13-2
1-benzyl-3-bromo-1H-pyrrole

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 439813-83-9
3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-1-(benzyl)-1H-pyrrole

Guidance literature:: With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; triethylamine; dichloro bis(acetonitrile) palladium(II); In toluene; at 90 ℃; for 24h;
DOI:10.1021/ja068577p