Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)

Base Information

Chemical Name:Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)
CAS No.:917499-87-7
Molecular Formula:C₈H₁₆O₁₀Rh₂
Molecular Weight:478.02
Hs Code.:

Synonyms:Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)

Suppliers and Price of Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 2 raw suppliers

Chemical Property of Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)

Chemical Property:

PSA：145.79000
LogP:-0.21070

Purity/Quality:: 99.0% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)

There total 14 articles about Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: dirhodium tetraacetate

: barium perchlorate trihydrate

: 917499-87-7,29998-99-0
dirhodium tetracetate dihydrate

: [Rh₂(CH₃CO₂)2(H₂O)6]⁽²⁺⁾*2ClO₄^(1-)=[Rh₂(CH₃CO₂)2(H₂O)6](ClO₄)2

: 106564-52-7
[Rh₂(CH₃CO₂)3(H₂O)4]⁽¹⁺⁾*ClO₄^(1-)=[Rh₂(CH₃CO₂)3(H₂O)4]ClO₄

Guidance literature:: With H₂SO₄; In sulfuric acid; byproducts: BaSO4, KClO4; aq. H2SO4; react. of (Rh2(CH3CO2)4) with H2SO4 (molar ratio 1:2); dissolving product in boiling H2O under Ar; addn. of excess Ba(ClO4)2*3H2O with stirring; cooling, filtering off ppt. of BaSO4; evapg. filtrate to min. vol. and passing through ion exchange column;; elution with H2O, 0.05 M and 0.5 M HClO4; adjusting HClO4-eluates to pH7 with aq. KOH-soln. (Ar), filtering, evapg. to dryness and drying in vac. desiccator (P2O5); dissolving in min. of abs. C2H5OH, filtering and evapg. to dryness; elem. anal.;;

Reference yield: 80.0%

: tetra[μ-acetato-bis(methanol)]dirhodium

: 4578-31-8
adenosine-5'-monophosphate disodium salt

: 917499-87-7,29998-99-0
dirhodium tetracetate dihydrate

: tetrakis-μ-acetato-dirhodium(II) adenosine-5'-monophosphate adduct

Guidance literature:: In water; slight excess of nucleotide, stirring for 5 h (dissoln.); pptn. on acetone addn.; elem. anal.;
DOI:10.1039/DT9790000596

Reference yield: 80.0%

: tetra[μ-acetato-bis(methanol)]dirhodium

: adenosine-5'-triphosphate disodium salt

: 917499-87-7,29998-99-0
dirhodium tetracetate dihydrate

: tetrakis-μ-acetato-dirhodium(II) adenosine-5'-triphosphate adduct

Guidance literature:: In water; slight excess of nucleotide, stirring for 5 h (dissoln.); pptn. on acetone addn.; elem. anal.;
DOI:10.1039/DT9790000596