2-(2-bromophenyl)-4,6-diphenyl-1,3,5-triazine

Base Information

• Chemical Name: 2-(2-bromophenyl)-4,6-diphenyl-1,3,5-triazine
• CAS No.: 77989-15-2
• Molecular Formula: C21H14BrN3
• Molecular Weight: 388.266
• Mol file: 77989-15-2.mol

Synonyms:2-(o-bromophenyl)-4,6-diphenyl-1,3,5-triazine

Chemical Property of 2-(2-bromophenyl)-4,6-diphenyl-1,3,5-triazine

Chemical Property:

• Melting Point: 142.0 to 146.0 °C
• Boiling Point: 582.8±52.0 °C(Predicted)
• PKA: 0.28±0.10(Predicted)
• PSA: 38.67000
• Density: 1.381±0.06 g/cm3(Predicted)
• LogP: 5.63510
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-(2-Bromophenyl)-4,6-diphenyl-1,3,5-triazine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(2-bromophenyl)-4,6-diphenyl-1,3,5-triazine

There total 4 articles about 2-(2-bromophenyl)-4,6-diphenyl-1,3,5-triazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

→ 2-(4’,6’-diphenyl-1’,3’,5’-triazinyl)bromobenzene (77989-15-2)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutyl-ammonium chloride; potassium carbonate; In ethanol; water; toluene; at 78 ℃; for 8h; Inert atmosphere;

Reference yield: 59.0%

benzamidine monohydrochloride (1670-14-0) + ortho-bromobenzaldehyde (6630-33-7) → 2-(4’,6’-diphenyl-1’,3’,5’-triazinyl)bromobenzene (77989-15-2)

Guidance literature:

With copper(II) acetate monohydrate; sodium carbonate; In toluene; at 100 ℃; for 24h;

DOI:10.1007/s10895-018-2235-2

Reference yield: 18.0%

1-phenylpentan-2-one (6683-92-7) → 3-propyl-4-phenyl-1,2,5-thiadiazole (77989-11-8) + 3-o-bromophenyl-4-phenyl-1,2,5-thiadiazole (77989-10-7) + 2-(4’,6’-diphenyl-1’,3’,5’-triazinyl)bromobenzene (77989-15-2)

Guidance literature:

With sulfur nitride; In toluene; for 24h; Heating;

upstream raw materials:

2'-bromo-2-phenylacetophenone

1-phenylpentan-2-one

benzamidine monohydrochloride

ortho-bromobenzaldehyde

Refernces

• 1、 Wang, Xueding,Xu, Yilian,Yang, Lu,Lu, Xiang,Zou, Hao,Yang, Weiqing,Zhang, Yuanyuan,Li, Zicheng,Ma, Menglin. "Synthesis, Spectra, and Theoretical Investigations of 1,3,5-Triazines Compounds as Ultraviolet Rays Absorber Based on Time-Dependent Density Functional Calculations and three-Dimensional Quantitative Structure-Property Relationship". . p. 707 - 723. Retrieved 2018/05/05.