4,5,9,10-TetrabroMo-2,7-dioctylbenzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone

Base Information

• Chemical Name: 4,5,9,10-TetrabroMo-2,7-dioctylbenzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone
• CAS No.: 954374-43-7
• Molecular Formula: C₃₀H₃₄Br₄N₂O₄
• Molecular Weight: 806.227
• Mol file: 954374-43-7.mol

Synonyms:4,5,9,10-TetrabroMo-2,7-dioctylbenzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone;4,5,9,10-Tetrabromo-2,7-dioctylbenzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone

Chemical Property of 4,5,9,10-TetrabroMo-2,7-dioctylbenzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone

Chemical Property:

• PSA: 78.14000
• LogP: 8.83660
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

4,5,9,10-Tetrabromo-2,7-dioctylbenzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4,5,9,10-TetrabroMo-2,7-dioctylbenzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone

There total 5 articles about 4,5,9,10-TetrabroMo-2,7-dioctylbenzo[lMn][3,8]phenanthroline-1,3,6,8-tetraone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

n-Octylamine (111-86-4) + 2,3,6,7-tetrabromonaphthalene-1,4,5,8-tetracarboxylic dianhydride (299962-88-2) → 2,3,6,7-tetrabromonaphthalene-1,8,4,5-tetracarboxylic acid N,N-dioctyldiimide (954374-43-7)

Guidance literature:

n-Octylamine; 2,3,6,7-tetrabromonaphthalene-1,4,5,8-tetracarboxylic dianhydride; In dichloromethane; for 2h; Reflux;

With phosphorus tribromide; In dichloromethane; for 1h; Reflux;

DOI:10.1016/j.tetlet.2013.02.075

Reference yield: 28.0%

n-Octylamine (111-86-4) + 2,3,6,7-tetrabromo-1,4,5,8-naphthalenetetracarboxylic acid diimide (943148-76-3) → 2,3,6,7-tetrabromonaphthalene-1,8,4,5-tetracarboxylic acid N,N-dioctyldiimide (954374-43-7)

Guidance literature:

n-Octylamine; 2,3,6,7-tetrabromo-1,4,5,8-naphthalenetetracarboxylic acid diimide; With acetic acid; at 120 ℃; Schlenk technique; Inert atmosphere;

With phosphorus tribromide; In toluene; Reflux; Inert atmosphere;

DOI:10.1002/chem.201402398

Reference yield:

1,4,5,8-naphthalenetetracarboxylic dianhydride (81-30-1) → 2,3,6,7-tetrabromonaphthalene-1,8,4,5-tetracarboxylic acid N,N-dioctyldiimide (954374-43-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 96 percent / Br₂; H₂SO₄; SO₃ / I₂ / 672000 h / 140 °C

2: AcOH / 0.5 h / 120 °C

3: 672 mg / PBr₃ / toluene / 12 h / Heating

With sulfuric acid; sulfur trioxide; bromine; phosphorus tribromide; acetic acid; iodine; In toluene;

DOI:10.1021/ol701539z

upstream raw materials:

2,3,6,7-tetrabromo-4,8-bis(octylcarbamoyl) naphthalene-1,5-dicarboxylic acid

1,4,5,8-naphthalenetetracarboxylic dianhydride

2,3,6,7-tetrabromonaphthalene-1,4,5,8-tetracarboxylic dianhydride

n-Octylamine

Downstream raw materials:

N,N′-di-(n-octyl)-2,7-dibromo-3,6-diphenylamino-1,4,5,8-naphthalenetetracarboxylic acid diimide

N,N′-di-(n-octyl)-2,3-dibromo-6,7-diphenylamino-1,4,5,8-naphthalenetetracarboxylic acid diimide

N,N′-di-(n-octyl)-2,6-dibromo-3,7-diphenylamino-1,4,5,8-naphthalenetetracarboxylic acid diimide