1-PHENYLVINYLBORONIC ACID, PROPANEDIOL CYCLIC ESTER

Base Information

Chemical Name:1-PHENYLVINYLBORONIC ACID, PROPANEDIOL CYCLIC ESTER
CAS No.:415727-02-5
Molecular Formula:C11H13BO2
Molecular Weight:188.033
Hs Code.:2934999090
Mol file:415727-02-5.mol

Synonyms:1-PHENYLVINYLBORONIC ACID, PROPANEDIOL CYCLIC ESTER;2-(1-Phenylvinyl)-1,3,2-dioxaborinane

Suppliers and Price of 1-PHENYLVINYLBORONIC ACID, PROPANEDIOL CYCLIC ESTER

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
2-(1-Phenylvinyl)-1,3,2-dioxaborinane 95+%
5g
$ 706.00

Matrix Scientific
2-(1-Phenylvinyl)-1,3,2-dioxaborinane 95+%
1g
$ 227.00

Crysdot
2-(1-Phenylvinyl)-1,3,2-dioxaborinane 95+%
25g
$ 452.00

American Custom Chemicals Corporation
2-(1-PHENYLVINYL)-1,3,2-DIOXABORINANE 95.00%
1G
$ 179.55

Alichem
2-(1-Phenylvinyl)-1,3,2-dioxaborinane
25g
$ 501.60

AK Scientific
1-Phenylvinylboronicacidpropanediolcyclicester
25g
$ 691.00

Total 11 raw suppliers

Chemical Property of 1-PHENYLVINYLBORONIC ACID, PROPANEDIOL CYCLIC ESTER

Chemical Property:

PSA：18.46000
LogP:2.16410
Storage Temp.:2-8°C

Purity/Quality:

97% ^*data from raw suppliers

2-(1-Phenylvinyl)-1,3,2-dioxaborinane 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1-PHENYLVINYLBORONIC ACID, PROPANEDIOL CYCLIC ESTER

There total 3 articles about 1-PHENYLVINYLBORONIC ACID, PROPANEDIOL CYCLIC ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 14900-39-1
phenylvinylboronic acid

: 504-63-2
trimethyleneglycol

: 415727-02-5
2-(1-phenylethenyl)-1,3,2-dioxabornane

Guidance literature:: With magnesium sulfate; In toluene; at 20 ℃;
DOI:10.1016/S0022-328X(01)01239-6

Reference yield: 66.0%

: 121-43-7,63156-11-6
Trimethyl borate

: 98-81-7
1-bromovinylbenzene

: 504-63-2
trimethyleneglycol

: 415727-02-5
2-(1-phenylethenyl)-1,3,2-dioxabornane

Guidance literature:: With magnesium; ethylene dibromide; In tetrahydrofuran; to Mg turnings and THF 1,2-dibromoethane followed by α-bromostyrene in THF were added, stirred at 80°C for 30 min, cooled to -78°C, soln. B(OMe)3 in THF was added dropwise and stirred at -78°C for 1 h and overnight at r.t.; react. mixt. was treated with aq. HCl, extracted with Et2O, evapd., dissolved in toluene, 1,3-propanediol was added and stirred with MgSO4 overnight at room temp., soln. was filtered, dried over MgSO4 and distilled under reduced pressure;
DOI:10.1016/S0022-328X(01)01239-6

Reference yield:

: 98-81-7
1-bromovinylbenzene

: 415727-02-5
2-(1-phenylethenyl)-1,3,2-dioxabornane

Guidance literature:: Multi-step reaction with 2 steps

1.1: Mg; 1,2-dibromoethane / tetrahydrofuran / 0.5 h / 80 °C

1.2: tetrahydrofuran / 1 h / -78 °C

2.1: 66 percent / MgSO₄ / toluene / 20 °C

With magnesium sulfate; magnesium; ethylene dibromide; In tetrahydrofuran; toluene;
DOI:10.1016/S0022-328X(01)01239-6