1,3-Bis(2,6-di(pentan-3-yl)phenyl)-1H-iMidazol-3-iuM chloride

Base Information

• Chemical Name: 1,3-Bis(2,6-di(pentan-3-yl)phenyl)-1H-iMidazol-3-iuM chloride
• CAS No.: 1157867-61-2
• Molecular Formula: C35H53ClN2
• Molecular Weight: 537.272
• Mol file: 1157867-61-2.mol

Synonyms:1,3-Bis(2,6-di(pentan-3-yl)phenyl)-1H-iMidazol-3-iuM chloride;CAS:1157867-61-2

Chemical Property of 1,3-Bis(2,6-di(pentan-3-yl)phenyl)-1H-iMidazol-3-iuM chloride

Chemical Property:

• PSA: 8.81000
• LogP: 7.37240
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

HPLC≥98% ^*data from raw suppliers

1,3-Bis(2,6-di(pentan-3-yl)phenyl)-1H-imidazol-3-iumChloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 1,3-Bis(2,6-di(pentan-3-yl)phenyl)-1H-imidazol-3-ium Chloride is used as a reactant in organic synthesis.

Technology Process of 1,3-Bis(2,6-di(pentan-3-yl)phenyl)-1H-iMidazol-3-iuM chloride

There total 10 articles about 1,3-Bis(2,6-di(pentan-3-yl)phenyl)-1H-iMidazol-3-iuM chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + N,N'-bis[2,6-di(pentan-3-yl)phenyl]diazabutadiene (1440435-02-8) → 1,3-bis[2,6-bis(pentan-3-yl)phenyl]-3H-1λ5-imidazol-1-ylium chloride (1157867-61-2)

Guidance literature:

N,N'-bis[2,6-di(pentan-3-yl)phenyl]diazabutadiene; With zinc(II) chloride; In tetrahydrofuran; at 70 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique;

formaldehyd; for 0.0166667h; Inert atmosphere; Schlenk technique;

With hydrogenchloride; In tetrahydrofuran; 1,4-dioxane; at 70 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201503941

Reference yield: 30.0%

→ 1,3-bis[2,6-bis(pentan-3-yl)phenyl]-3H-1λ5-imidazol-1-ylium chloride (1157867-61-2)

Guidance literature:

With sodium tetrahydroborate; In tetrahydrofuran; at 0 - 20 ℃; for 3h;

With ammonium chloride; In tetrahydrofuran;

Reference yield:

2,6-bis(1-ethylpropyl)aniline → 1,3-bis[2,6-bis(pentan-3-yl)phenyl]-3H-1λ5-imidazol-1-ylium chloride (1157867-61-2)

Guidance literature:

Multi-step reaction with 2 steps

1: formic acid / methanol; water / 3 h / 20 °C

2: zinc(II) chloride; hydrogenchloride / tetrahydrofuran; 1,4-dioxane / 3 h / 70 °C

With hydrogenchloride; formic acid; zinc(II) chloride; In tetrahydrofuran; 1,4-dioxane; methanol; water;

DOI:10.1021/om400168b

upstream raw materials:

formaldehyd

N,N'-bis[2,6-di(pentan-3-yl)phenyl]diazabutadiene

2,6-dimethylnitrobenzene

2-nitroisophthalic acid