alpha-D-ribo-Hexopyranoside,methyl2,3,6-trideoxy-2-[[(phenylmethoxy)carbonyl]amino]-(9CI)

Base Information

Chemical Name:alpha-D-ribo-Hexopyranoside,methyl2,3,6-trideoxy-2-[[(phenylmethoxy)carbonyl]amino]-(9CI)
CAS No.:494868-08-5
Molecular Formula:C15H21NO5
Molecular Weight:295.33
Hs Code.:
Mol file:494868-08-5.mol

Synonyms:alpha-D-ribo-Hexopyranoside,methyl2,3,6-trideoxy-2-[[(phenylmethoxy)carbonyl]amino]-(9CI)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of alpha-D-ribo-Hexopyranoside,methyl2,3,6-trideoxy-2-[[(phenylmethoxy)carbonyl]amino]-(9CI)

Chemical Property:

Boiling Point:472.1±45.0 °C(Predicted)
PKA:10.96±0.70(Predicted)
Density:1.21±0.1 g/cm3(Predicted)

Purity/Quality:

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Technology Process of alpha-D-ribo-Hexopyranoside,methyl2,3,6-trideoxy-2-[[(phenylmethoxy)carbonyl]amino]-(9CI)

There total 3 articles about alpha-D-ribo-Hexopyranoside,methyl2,3,6-trideoxy-2-[[(phenylmethoxy)carbonyl]amino]-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 79698-62-7
Benzoic acid (2R,3S,5R,6S)-5-benzyloxycarbonylamino-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester

: 494868-08-5
((2S,3R,5S,6R)-5-Hydroxy-2-methoxy-6-methyl-tetrahydro-pyran-3-yl)-carbamic acid benzyl ester

Guidance literature:: With sodium methylate; In methanol;
DOI:10.1021/ja00410a056

Reference yield:

: 79698-61-6,80734-77-6
((2R,4aR,6S,7S,8aR)-8-Iodo-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-carbamic acid benzyl ester

: 494868-08-5
((2S,3R,5S,6R)-5-Hydroxy-2-methoxy-6-methyl-tetrahydro-pyran-3-yl)-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NBS, BaCO₃, 2.) Bu₃SnH, AIBN / 1.) CCl₄, reflux, 2.) toluene, 80 - 90 deg C

2: NaOMe / methanol

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; sodium methylate; barium carbonate; In methanol;
DOI:10.1021/ja00410a056

Reference yield:

: 79698-60-5
Imidazole-1-sulfonic acid (2R,4aR,6S,7R,8R,8aR)-7-benzyloxycarbonylamino-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester

: 494868-08-5
((2S,3R,5S,6R)-5-Hydroxy-2-methoxy-6-methyl-tetrahydro-pyran-3-yl)-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / Bu₄I / benzene / 4 h / Heating

2: 1.) NBS, BaCO₃, 2.) Bu₃SnH, AIBN / 1.) CCl₄, reflux, 2.) toluene, 80 - 90 deg C

3: NaOMe / methanol

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; sodium methylate; barium carbonate; In methanol; benzene;
DOI:10.1021/ja00410a056