2-Hexenylmalonic acid dimethyl ester

Base Information

Chemical Name:2-Hexenylmalonic acid dimethyl ester
CAS No.:74810-84-7
Molecular Formula:C₁₁H₁₈O₄
Molecular Weight:214.262
Hs Code.:
Mol file:74810-84-7.mol

Synonyms:2-(2-Hexenyl)malonic acid dimethyl ester;2-(2-Hexenyl)propanedioic acid dimethyl ester;2-Hexenylmalonic acid dimethyl ester

Suppliers and Price of 2-Hexenylmalonic acid dimethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of 2-Hexenylmalonic acid dimethyl ester

Chemical Property:

PSA：52.60000
LogP:1.69500

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-Hexenylmalonic acid dimethyl ester

There total 10 articles about 2-Hexenylmalonic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1-chloro-4-(hex-1-en-3-ylsulfonyl)benzene

: 108-59-8
malonic acid dimethyl ester

: 77517-66-9
Dimethyl(1-propylprop-2-enyl) malonate

: 74810-84-7
dimethyl 2-hexenylmalonate

Guidance literature:: malonic acid dimethyl ester; With sodium hydride; In tetrahydrofuran; Inert atmosphere;

1-chloro-4-(hex-1-en-3-ylsulfonyl)benzene; With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; 1,3-bis-(diphenylphosphino)propane; N-ethyl-N,N-diisopropylamine; cobalt(II) bromide; In tetrahydrofuran; at 20 ℃; for 18h; regioselective reaction; Inert atmosphere; Sealed tube; Irradiation; Molecular sieve;
DOI:10.1055/s-0040-1707524

Reference yield: 47.0%

: 34686-76-5
1-bromo-2-hexene

: 108-59-8
malonic acid dimethyl ester

: 74810-84-7
dimethyl 2-hexenylmalonate

Guidance literature:: With potassium carbonate; In acetonitrile; at 80 ℃; for 16h;
DOI:10.1021/ol3028913

Reference yield:

: 83135-00-6
(hex-1-en-3-yl)methyl carbonate

: 108-59-8
malonic acid dimethyl ester

: 77517-66-9
Dimethyl(1-propylprop-2-enyl) malonate

: 74810-84-7
dimethyl 2-hexenylmalonate

Guidance literature:: malonic acid dimethyl ester; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.333333h;

(hex-1-en-3-yl)methyl carbonate; di(rhodium)tetracarbonyl dichloride; In tetrahydrofuran; at 20 ℃; Further stages. Title compound not separated from byproducts.;
DOI:10.1021/jo701290b