2-(2,3-dihydro-1H-inden-4-yl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane

Base Information

• Chemical Name: 2-(2,3-dihydro-1H-inden-4-yl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane
• CAS No.: 1252793-57-9
• Molecular Formula: C15H21BO2
• Molecular Weight: 244.142
• Mol file: 1252793-57-9.mol

Synonyms:2-(2,3-dihydro-1H-inden-4-yl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane

Chemical Property of 2-(2,3-dihydro-1H-inden-4-yl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane

Chemical Property:

• Boiling Point: 355.4±31.0 °C(Predicted)
• PSA: 18.46000
• Density: 1.04±0.1 g/cm3(Predicted)
• LogP: 2.47450
• Storage Temp.: 2-8°C

Purity/Quality:

98% ^*data from raw suppliers

2-(2,3-dihydro-1H-inden-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(2,3-dihydro-1H-inden-4-yl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane

There total 5 articles about 2-(2,3-dihydro-1H-inden-4-yl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (61676-62-8) + 4-bromo-2,3-dihydro-1H-indene (6134-53-8) → 2-(2,3-dihydro-1H-inden-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1252793-57-9)

Guidance literature:

With n-butyllithium;

Reference yield: 100.0%

C25H42B2O5 (1252793-70-6) → 2-(2,3-dihydro-1H-inden-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1252793-57-9)

Guidance literature:

In N,N-dimethyl-formamide; at 80 ℃; for 6h; Inert atmosphere;

DOI:10.1002/chem.201000486

Reference yield: 57.0%

4-bromo-2,3-dihydro-1H-indene (6134-53-8) + bis(pinacol)diborane (73183-34-3) → 2-(2,3-dihydro-1H-inden-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1252793-57-9)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In 1,4-dioxane; at 90 ℃; for 4h; Inert atmosphere;

upstream raw materials:

C₂₅H₄₂B₂O₅

4-bromo-2,3-dihydroinden-1-one

3-(2-bromophenyl)propionic acid

4-bromo-2,3-dihydro-1H-indene

Refernces

• 1、 -. "ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES". . . Retrieved 2022/01/04.
• 2、 Lebuf, David,Iannazzo, Laura,Geny, Anais,Malacria, Max,Peter C Vollhardt,Aubert, Corinne,Gandon, Vincent. "Cobalt-mediated linear 2:1 Co-oligomerization of alkynes with enol ethers to give 1-alkoxy-1,3,5-trienes: A missing mode of reactivity". scheme or table. p. 8904 - 8913. Retrieved 2010/10/21.