TETRAKIS(DIMETHYLSULFOXIDE)DICHLORORUTHENIUM (II)

Base Information

• Chemical Name: TETRAKIS(DIMETHYLSULFOXIDE)DICHLORORUTHENIUM (II)
• CAS No.: 11070-19-2
• Molecular Formula: C₈H₂₄O₄RuS₄*2Cl
• Molecular Weight: 484.516
• Mol file: 11070-19-2.mol

Synonyms:-6-22)-;dichloro(sulfinylbis(methane)-o)tris(sulfinylbis(methane)-s)-rutheniu(oc;dichlorotetrakis(dimethylsulfoxide)ruthenium(ii);dichlorotetrakis(dimethylsulfoxide)rutheniumii;dichlorotetrakis(methylsulfoxide)-rutheniu;dichlorotetrakis(methylsulfoxide)ruthenium;dichlorotetrakis(sulfinylbis(methane))-rutheniu;dichlorotetrakis(sulfinylbis(methane))ruthenium

Chemical Property of TETRAKIS(DIMETHYLSULFOXIDE)DICHLORORUTHENIUM (II)

Chemical Property:

• Vapor Pressure: 0.805mmHg at 25°C
• Boiling Point: 189°C at 760 mmHg
• Flash Point: 85°C
• PSA: 145.12000
• LogP: 4.82060

Purity/Quality:

99%, ^*data from raw suppliers

cis-Tetrakis(dimethylsulfoxide)dichlororuthenium(II), 98% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Refernces

Shape-persistent, ruthenium(ii)- and iron(ii)-bisterpyridine metallodendrimers: Synthesis, traveling-wave ion-mobility mass spectrometry, and photophysical properties

10.1039/c2nj20799k

The study focuses on the synthesis, characterization, and investigation of the photophysical and electrochemical properties of shape-persistent metallodendrimers based on htpy-RuII-tpyi or htpy-FeII-tpyi connectivity. These metallodendrimers were developed using a self-assembly strategy and were fully characterized by techniques such as 1H and 13C NMR, traveling wave ion mobility mass spectrometry (TWIM MS), single crystal X-ray, UV-vis absorption, photoluminescence, and cyclic voltammetry. The researchers observed a significant increase in drift times with increasing generation of these complexes, correlating with the change in molecular size. Additionally, the photophysical properties, such as molar extinction coefficients, and electrochemical stability of the complexes varied noticeably with size and metal ion center, suggesting potential applications in catalysis, sensing, and light-harvesting devices.

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