2-Bromo-4'-methylbenzophenone

Base Information

• Chemical Name: 2-Bromo-4'-methylbenzophenone
• CAS No.: 67104-64-7
• Molecular Formula: C14H11BrO
• Molecular Weight: 275.145
• Hs Code.: 2914700090
• DSSTox Substance ID: DTXSID10450592
• Nikkaji Number: J1.089.803J
• Wikidata: Q82270380

Synonyms:2-BROMO-4'-METHYLBENZOPHENONE;67104-64-7;(2-bromophenyl)-(4-methylphenyl)methanone;MFCD09801674;2'-Bromo-4-methylbenzophenone;SCHEMBL3132601;DTXSID10450592;AKOS009347548

Chemical Property of 2-Bromo-4'-methylbenzophenone

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 376.46°C at 760 mmHg
• Flash Point: 79.767°C
• PSA: 17.07000
• Density: 1.376g/cm³
• LogP: 3.98850
• XLogP3: 4.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 273.99933
• Heavy Atom Count: 16
• Complexity: 243

Purity/Quality:

97% ^*data from raw suppliers

2-Bromo-4'-methylbenzophenone 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)C(=O)C2=CC=CC=C2Br

Technology Process of 2-Bromo-4'-methylbenzophenone

There total 14 articles about 2-Bromo-4'-methylbenzophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(2-bromophenyl)(p-tolyl)methanol (59142-66-4) → 2-bromophenyl(4-methylphenyl)methanone (67104-64-7)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1002/adsc.201500953

Reference yield: 86.0%

S-2-(tert-butylcarbamoyl)phenyl 4-methylbenzothioate (1002759-82-1) + (2-bromophenyl)boronic acid (244205-40-1) → 2-bromophenyl(4-methylphenyl)methanone (67104-64-7)

Guidance literature:

With air; Cu(I)-3-methylsalicylate; In N,N-dimethyl-formamide; at 50 ℃;

DOI:10.1021/ja074931n

Reference yield: 70.0%

o-cyanobromobenzene (2042-37-7) + sodium 4-methylbenzenesulfinate (824-79-3) → 2-bromophenyl(4-methylphenyl)methanone (67104-64-7)

Guidance literature:

With palladium(II) trifluoroacetate; trifluoroacetic acid; 6-methyl-2,2'-bipyridine; In tetrahydrofuran; water; at 100 ℃; for 1h; Microwave irradiation;

DOI:10.1021/jo501875n

upstream raw materials:

toluene

2-bromobenzoic-acid

o-cyanobromobenzene

S-2-(tert-butylcarbamoyl)phenyl 4-methylbenzothioate

Downstream raw materials:

[1,1'-biphenyl]-2,2'-diylbis(p-tolylmethanone)

1-bromo-2-(4-methylbenzyl)benzene

10,10-dibenzyl-3-methyl-5-phenyl-5,10-dihydro-acridarsine

cis-9,10-dihydroxy-9,10-bis(4-methylphenyl)-9,10-dihydrophenanthrene

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