3-Methylperylene

Base Information

• Chemical Name: 3-Methylperylene
• CAS No.: 24471-47-4
• Molecular Formula: C₂₁H₁₄
• Molecular Weight: 266.342
• UNII: S1XG38HY95
• DSSTox Substance ID: DTXSID30179233
• Nikkaji Number: J344.875D
• Wikidata: Q83049733
• Mol file: 24471-47-4.mol

Synonyms:3-METHYLPERYLENE;Perylene, 3-methyl-;24471-47-4;S1XG38HY95;3-Methylperylen;3-Methylperylene #;UNII-S1XG38HY95;DTXSID30179233;DZFULQFHDSYXKM-UHFFFAOYSA-N

Chemical Property of 3-Methylperylene

Chemical Property:

• Vapor Pressure: 6.9E-09mmHg at 25°C
• Melting Point: 214-215 °C
• Boiling Point: 479.4°Cat760mmHg
• Flash Point: 236.7°C
• PSA: 0.00000
• Density: 1.254g/cm³
• LogP: 6.04560
• XLogP3: 6.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 266.109550447
• Heavy Atom Count: 21
• Complexity: 399

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C2C=CC=C3C2=C(C=C1)C4=CC=CC5=C4C3=CC=C5

Technology Process of 3-Methylperylene

There total 5 articles about 3-Methylperylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

Trimethylboroxine (823-96-1) + 3-Nitroperylene (20589-63-3) → 3-Methyl-perylen (24471-47-4)

Guidance literature:

With dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine; palladium diacetate; caesium carbonate; In toluene; at 150 ℃; for 24h; Inert atmosphere;

DOI:10.1039/d0sc01641a

Reference yield:

perylene-3-carbaldehyde (35438-63-2) → 3-Methyl-perylen (24471-47-4)

Guidance literature:

With hydrazine hydrate; at 300 ℃;

Reference yield:

PERYLENE (198-55-0) + methyllithium (917-54-4) → 3-Methyl-perylen (24471-47-4)

Guidance literature:

With sodium thiosulfate; lithium bromide; Yield given; Multistep reaction; 1.) THF, -78 deg C, 2.) THF;

DOI:10.1021/jp9845219

upstream raw materials:

perylene-3-carbaldehyde

methyl magnesium iodide

PERYLENE

methyllithium