Tetrakis(triethyl phosphite)nickel(0)

Base Information

• Chemical Name: Tetrakis(triethyl phosphite)nickel(0)
• CAS No.: 14839-39-5
• Molecular Formula: C₂₄H₆₀NiO₁₂P₄
• Molecular Weight: 723.318
• Mol file: 14839-39-5.mol

Synonyms:Tetrakis(triethyl phosphite)nickel(0)

Chemical Property of Tetrakis(triethyl phosphite)nickel(0)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tetrakis(triethyl phosphite)nickel(0)

There total 5 articles about Tetrakis(triethyl phosphite)nickel(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetracarbonyl nickel (13463-39-3,71564-36-8) + triethyl phosphite (122-52-1) → tetrakis(triethylphosphite)nickel(0) (14839-39-5)

Guidance literature:

In neat (no solvent); byproducts: CO; slow heating mixt. of (Ni(CO)4) and P(OC2H5)3 from -80°C to 180°C (reflux temp.), cooling down after 18 h (when CO evolution stopped);; pptn., recrystn. from abs. alc.;;

Reference yield:

diacetyldicyclohexylimine-N-p-tolylsulfinylaminenickel(0) (156882-24-5) + triethyl phosphite (122-52-1) → tetrakis(triethylphosphite)nickel(0) (14839-39-5) + Ni{(P(OC2H5)3)2}(CH3C6H4NSO)2

Guidance literature:

In not given;

Reference yield:

glyoxalbis(2,6-diisopropylphenylimine)-N-phenylsulfinylaminenickel(0) (156882-11-0) + triethyl phosphite (122-52-1) → tetrakis(triethylphosphite)nickel(0) (14839-39-5) + Ni{(P(OC2H5)3)2}(C6H5NSO)2

Guidance literature:

In not given;

upstream raw materials:

tetracarbonyl nickel

triethyl phosphite

diacetyldicyclohexylimine-N-p-tolylsulfinylaminenickel⁽⁰⁾

glyoxalbis(2,6-diisopropylphenylimine)-N-phenylsulfinylaminenickel⁽⁰⁾

Downstream raw materials:

triethyl phosphite

nickel(II) iodide