Nickel tetracarbonyl

Base Information Edit

Chemical Name:Nickel tetracarbonyl
CAS No.:13463-39-3
Deprecated CAS:13005-31-7,14875-95-7,36252-60-5,42126-46-5,71327-12-3,848779-18-0
Molecular Formula:C₄NiO₄
Molecular Weight:170.732
Hs Code.:
European Community (EC) Number:236-669-2
DSSTox Substance ID:DTXSID0024212
Wikipedia:Nickel tetracarbonyl,Nickel_tetracarbonyl
Mol file:13463-39-3.mol

Synonyms:nickel carbonyl;nickel tetracarbonyl

Suppliers and Price of Nickel tetracarbonyl

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
Nickel carbonyl
450g
$ 5076.00

Strem Chemicals
Nickel carbonyl
100g
$ 3626.00

Total 0 raw suppliers

Chemical Property of Nickel tetracarbonyl Edit

Chemical Property:

Appearance/Colour:colourless liquid with a musty odour
Vapor Pressure:321 mmHg at 20 °C
Melting Point:-19°C
Boiling Point:43°C
Flash Point:<-20℃
PSA：0.00000
Density:1,32g/cm3
LogP:-0.83200
Sensitive.:heat sensitive
Water Solubility.:soluble in ~5000 parts air free H2O; soluble alcohol, benzene, chloroform, acetone, CCl4 [MER06]
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:169.915000
Heavy Atom Count:9
Complexity:76.5

Purity/Quality:: Nickel carbonyl ^*data from reagent suppliers

Safty Information:

Pictogram(s): Flammable, dangerous fire risk, explodes at 60C (140F). A carcinogen (OSHA). TLV: 0.05 ppm(Ni).
Hazard Codes:F,T+,N
Statements: 11-26-40-50/53-61
Safety Statements: 45-53-60-61

MSDS Files:

Useful:

Canonical SMILES:[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ni]
Uses Purification intermediate in refining nickel; catalyst in the petroleum, plastic, and rubber industries Nickel carbonyl is used in nickel vapoplating processes in the metallurgical and electronics industry, and in the catalytic methyl- and ethylacrylate monomer synthesis. For many years it had been used to produce pure nickel by the Mond process, which has been considered to be outdated since around 1970. Nickel tetracarbonyl is used in the manufactureof nickel powder and nickel-coatedmetals, and as a catalyst in carboxylation,coupling, and cyclization reactions. It canform from the contact of carbon monoxidewith nickel. In organic synthesis; production of high-purity nickel powder and continuous nickel coatings on steel and other metals.
Description Nickel carbonyl is a clear colourless to yellow volatile liquid, is flammable, and burns with a yellow flame. It is denser than water and insoluble in water but soluble in alcohol, benzene, chloroform, acetone, ethanol, carbon tetrachloride, and nitric acid. The vapours are heavier than air. In industries, nickel carbonyl is used in nickel coat steel and other metals and to make very pure nickel. Nickel carbonyl gets peroxidised by air as a solid deposit and decomposes to ignite.
Physical properties Colorless volatile liquid; diamagnetic; flammable; burns with a bright luminous flame; density 1.319 g/mL; freezes at -25°C; boils at 43°C; vapor pressure 320.6 torr at 20°C; vapor density 5.89 (air=1); critical temperature about 200°C; critical pressure 30 atm; practically insoluble in water, 180 mg/L at 10°C; miscible with most organic solvents including ethanol, acetone, and benzene; soluble in nitric acid and aqua regia.

Technology Process of Nickel tetracarbonyl

There total 354 articles about Nickel tetracarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: [Ni(1,3-di-tert-butyl-imidazolin-2-ylidene)(CO)₂]

: 201230-82-2
carbon monoxide

: [(ImN(t-Bu)2)Ni(CO)3]

: 13463-39-3,71564-36-8
tetracarbonyl nickel

Guidance literature:: In not given; byproducts: C3H2N2(C(CH3)3)2; High Pressure; not isolated, detected by IR;
DOI:10.1021/ja0438821

Reference yield: 99.0%

: [(N,N'-bis(1-adamantylimidazol)-2-ylidene)Ni(CO)2]

: 201230-82-2
carbon monoxide

: [(ImN(adamantyl)2)Ni(CO)3]

: 13463-39-3,71564-36-8
tetracarbonyl nickel

Guidance literature:: In not given; byproducts: C3H2N2(C10H15)2; High Pressure; not isolated, detected by IR;
DOI:10.1021/ja0438821

Reference yield: 75.0%

: 7440-02-0
nickel

: 13463-39-3,71564-36-8
tetracarbonyl nickel

Guidance literature:: With carbon monoxide; lithium perchlorate; In methanol; Electrochem. Process; CO 50 bar, electrolysis (Ni-anode, Bu4NBr, 293 K, 50 mA, 4.0 V, 120 h); distn., dried (P2O5);