D-[11-13C]TALOSE

Base Information

• Chemical Name: D-[11-13C]TALOSE
• CAS No.: 70849-29-5
• Molecular Formula: C₆H₁₂O₆
• Molecular Weight: 181.147
• Mol file: 70849-29-5.mol

Synonyms:D-[11-13C]TALOSE;D-Talose-1-13C;d-[1-13C]talose

Chemical Property of D-[11-13C]TALOSE

Chemical Property:

• PSA: 110.38000
• LogP: -3.22140
• Storage Temp.: -20°C
• Solubility.: DMSO (Slightly), Methanol (Slightly), Water (Slightly)

Purity/Quality:

97% ^*data from raw suppliers

D-Talose-1-13C ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: D-Talose is a monosaccharide sugar that can convert between aldose and ketose forms in pyridine in the presence of aluminum oxide. This is the labeled isomer.

Technology Process of D-[11-13C]TALOSE

There total 6 articles about D-[11-13C]TALOSE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

<1-13C>-α-D-talopyranose (40010-55-7,40010-56-8,56746-22-6,60821-16-1,60821-17-2,60821-20-7,60821-21-8) → <1-13C>-D-talose (70849-29-5,478519-02-7) + D-[1-13C]talose hydrate + <1-13C>-α-D-talofuranose + <1-13C>-β-D-talofuranose + β-D-[1-13C]talopyranose (40010-55-7,40010-56-8,56746-22-6,60821-16-1,60821-17-2,60821-20-7,60821-21-8)

Guidance literature:

With sodium acetate; acetic acid; In water-d2; at 28 ℃; Product distribution; Equilibrium constant; Rate constant;

DOI:10.1021/ja00189a050

Reference yield:

D-lyxose (1114-34-7) + potassium [13C]cyanide → <1-13C>-D-talose (70849-29-5,478519-02-7) + <1-13C>-D-galactose (70849-30-8,478519-02-7)

Guidance literature:

With hydrogen; Pd-BaSO₄; Multistep reaction; 1.) pH 7.2-7.5;

DOI:10.1021/ja00246a001

Reference yield:

<1-13C>-α-D-talofuranose → <1-13C>-D-talose (70849-29-5,478519-02-7)

Guidance literature:

With sodium acetate; acetic acid; In water-d2; at 41 - 71 ℃; Kinetics; Thermodynamic data; E(act);

DOI:10.1021/ja00189a050

upstream raw materials:

D-lyxose

β-D-[1-13C]talopyranose

<1-13C>-α-D-talopyranose

Downstream raw materials:

D-(1-13C)talitol