rac 2-Hydroxy-4,6-dimethoxy-benzoic Acid 1-Methyl-5-oxo-9-decen-1-yl Ester

Base Information

Chemical Name:rac 2-Hydroxy-4,6-dimethoxy-benzoic Acid 1-Methyl-5-oxo-9-decen-1-yl Ester
CAS No.:312305-40-1
Molecular Formula:C20H28O6
Molecular Weight:364.43272
Hs Code.:
DSSTox Substance ID:DTXSID40441918
Nikkaji Number:J1.496.686B
Mol file:312305-40-1.mol

Synonyms:312305-40-1;rac 2-Hydroxy-4,6-dimethoxy-benzoic Acid 1-Methyl-5-oxo-9-decen-1-yl Ester;6-oxoundec-10-en-2-yl 2-hydroxy-4,6-dimethoxybenzoate;AGN-PC-0N6SA1;DTXSID40441918;GIQVBZLNKRMWBN-UHFFFAOYSA-N;FT-0669551;2-Hydroxy-4,6-dimethoxybenzoic acid 1-methyl-5-oxo-9-decenyl ester

Suppliers and Price of rac 2-Hydroxy-4,6-dimethoxy-benzoic Acid 1-Methyl-5-oxo-9-decen-1-yl Ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
rac2-Hydroxy-4,6-dimethoxy-benzoicAcid1-Methyl-5-oxo-9-decen-1-ylEster
500 mg
$ 690.00

Total 2 raw suppliers

Chemical Property of rac 2-Hydroxy-4,6-dimethoxy-benzoic Acid 1-Methyl-5-oxo-9-decen-1-yl Ester

Chemical Property:

Boiling Point:523.7±50.0 °C(Predicted)
PKA:7.15±0.40(Predicted)
PSA：82.06000
Density:1.099±0.06 g/cm3(Predicted)
LogP:4.05040
Solubility.:Dichloromethane, Ethyl Acetate,
XLogP3:4.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:13
Exact Mass:364.18858861
Heavy Atom Count:26
Complexity:450

Purity/Quality:

97% ^*data from raw suppliers

rac2-Hydroxy-4,6-dimethoxy-benzoicAcid1-Methyl-5-oxo-9-decen-1-ylEster ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(CCCC(=O)CCCC=C)OC(=O)C1=C(C=C(C=C1OC)OC)O
Uses Intermediate in the production of Zearalenone

Technology Process of rac 2-Hydroxy-4,6-dimethoxy-benzoic Acid 1-Methyl-5-oxo-9-decen-1-yl Ester

There total 3 articles about rac 2-Hydroxy-4,6-dimethoxy-benzoic Acid 1-Methyl-5-oxo-9-decen-1-yl Ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 3187-19-7
2,4-dimethoxysalicylic acid

: 17846-96-7
10-hydroxy-undec-1-en-6-one

: 312305-40-1
2-hydroxy-4,6-dimethoxybenzoic acid 1-methyl-5-oxo-dec-9-enyl ester

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In diethyl ether; at 20 ℃; for 3h;
DOI:10.1021/jo0009999

Reference yield:

: 34164-50-6
4-penten-1-ylmagnesium bromide

: 312305-40-1
2-hydroxy-4,6-dimethoxybenzoic acid 1-methyl-5-oxo-dec-9-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 77 percent / diethyl ether; tetrahydrofuran / -78 - 20 °C

2: 64 percent / PPh₃; DEAD / diethyl ether / 3 h / 20 °C

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; diethyl ether; 1: Grignard reaction / 2: Esterification;
DOI:10.1021/jo0009999

Reference yield:

: 823-22-3,26991-67-3
5-hexanolide

: 312305-40-1
2-hydroxy-4,6-dimethoxybenzoic acid 1-methyl-5-oxo-dec-9-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 77 percent / diethyl ether; tetrahydrofuran / -78 - 20 °C

2: 64 percent / PPh₃; DEAD / diethyl ether / 3 h / 20 °C

With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; diethyl ether; 1: Grignard reaction / 2: Esterification;
DOI:10.1021/jo0009999