(1S,8aS)-1,2,3,5,6,7,8,8a-Octahydro-1,4-dimethyl-7-(1-methylethylidene)azulene

Base Information

Chemical Name:(1S,8aS)-1,2,3,5,6,7,8,8a-Octahydro-1,4-dimethyl-7-(1-methylethylidene)azulene
CAS No.:3772-93-8
Molecular Formula:C15H24
Molecular Weight:204.356
Hs Code.:
UNII:LJZ6Q98YHV
DSSTox Substance ID:DTXSID601137341
Nikkaji Number:J14.456H
Mol file:3772-93-8.mol

Synonyms:3772-93-8;(1S,8aS)-1,2,3,5,6,7,8,8a-Octahydro-1,4-dimethyl-7-(1-methylethylidene)azulene;Bulnesene, beta-;LJZ6Q98YHV;DTXSID601137341;Guaia-1(10),7(11)-diene;Azulene, 1,2,3,5,6,7,8,8a-octahydro-1,4-dimethyl-7-(1-methylethylidene)-, (1S,8aS)-;Azulene, 1,2,3,5,6,7,8,8a-octahydro-1,4-dimethyl-7-(1-methylethylidene)-, (1S-trans)-

Suppliers and Price of (1S,8aS)-1,2,3,5,6,7,8,8a-Octahydro-1,4-dimethyl-7-(1-methylethylidene)azulene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (1S,8aS)-1,2,3,5,6,7,8,8a-Octahydro-1,4-dimethyl-7-(1-methylethylidene)azulene

Chemical Property:

PSA：0.00000
LogP:4.86930
XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:204.187800766
Heavy Atom Count:15
Complexity:313

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1CCC2=C(CCC(=C(C)C)CC12)C
Isomeric SMILES:C[C@H]1CCC2=C(CCC(=C(C)C)C[C@@H]12)C

Technology Process of (1S,8aS)-1,2,3,5,6,7,8,8a-Octahydro-1,4-dimethyl-7-(1-methylethylidene)azulene

There total 53 articles about (1S,8aS)-1,2,3,5,6,7,8,8a-Octahydro-1,4-dimethyl-7-(1-methylethylidene)azulene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 22451-73-6
2-(3,8-dimethyl-1,2,3,3a,4,5,6,7-octahydro-5-azulenyl)-2-propanol

: 20149-50-2
Guaioxide

: 489-81-6,3691-11-0,28890-02-0,29026-00-4,31682-28-7
δ-guaiene

: 3691-12-1,53863-54-0
(1S,4S,7R)-7-Isopropenyl-1,4-dimethyl-1,2,3,4,5,6,7,8-octahydro-azulene

: 3772-93-8
β-bulnesene

Guidance literature:: With montmorillonite K₁₀; In dichloromethane; at 20 ℃; for 0.5h; Reagent/catalyst;
DOI:10.1021/acs.jnatprod.6b01068

Reference yield:

: 59822-10-5
(+/-)-5-bromo-3-methyl-1-pentene

: 3772-93-8,31756-35-1,76036-00-5,97233-31-3
(+/-)-β-bulnesene

Guidance literature:: Multi-step reaction with 10 steps

1: 80 percent / Mg

2: m-chloroperoxybenzoic acid / CH₂Cl₂

3: pyridine

4: acetonitrile / 20 h / 150 °C

5: 73 percent / H₂ / 5percent Pd-C / ethanol

6: 77 percent

7: SOCl₂, HMPA

8: 76 percent / Na / diethyl ether / Ambient temperature

9: 70 percent / CrO₃ / pyridine

With chromium(VI) oxide; N,N,N,N,N,N-hexamethylphosphoric triamide; thionyl chloride; hydrogen; sodium; magnesium; 3-chloro-benzenecarboperoxoic acid; palladium on activated charcoal; In pyridine; diethyl ether; ethanol; dichloromethane; acetonitrile;
DOI:10.1039/c39830000666

Reference yield:

: 59822-10-5
(+/-)-5-bromo-3-methyl-1-pentene

: 3772-93-8,31756-35-1,76036-00-5,97233-31-3
(+/-)-4-epi-β-bulnesene

Guidance literature:: Multi-step reaction with 10 steps

1: 80 percent / Mg

2: m-chloroperoxybenzoic acid / CH₂Cl₂

3: pyridine

4: acetonitrile / 20 h / 150 °C

5: 73 percent / H₂ / 5percent Pd-C / ethanol

6: 77 percent

7: SOCl₂, HMPA

8: 76 percent / Na / diethyl ether / Ambient temperature

9: 70 percent / CrO₃ / pyridine

With chromium(VI) oxide; N,N,N,N,N,N-hexamethylphosphoric triamide; thionyl chloride; hydrogen; sodium; magnesium; 3-chloro-benzenecarboperoxoic acid; palladium on activated charcoal; In pyridine; diethyl ether; ethanol; dichloromethane; acetonitrile;
DOI:10.1039/c39830000666