20149-50-2

Usage

Uses

Used in Research and Chemical Synthesis:
(3R,6aα)-Decahydro-2,2,6α,9α-tetramethyl-3,9aβ-methano-cyclopent[b]oxocin is used as a research tool for studying chemical reactions and complex organic compounds due to its distinct molecular arrangement.
Used in Industrial and Pharmaceutical Applications:
(3R,6aα)-Decahydro-2,2,6α,9α-tetramethyl-3,9aβ-methano-cyclopent[b]oxocin is used as a building block for the synthesis of new chemicals and materials, making it valuable in various industries and pharmaceutical applications.

InChI:InChI=1/C15H26O/c1-10-5-7-12-9-15(16-14(12,3)4)11(2)6-8-13(10)15/h10-13H,5-9H2,1-4H3/t10-,11-,12+,13+,15?/m0/s1

Upstream product

• 49748-18-7 2-(2-carboxyethyl)-3-isopropenyl-1-methyl-cyclopent-1-ene 
• 145397-96-2 (3R,3aS,5R,8aR)-5-(1-Hydroxy-1-methyl-ethyl)-3-methyl-8-methylene-octahydro-azulen-3a-ol 
• 145397-94-0 8-Hydroxy-2-methyl-6-methylene-11-oxa-tricyclo[7.2.1.0^1,5]dodecan-10-one 
• 145512-09-0 3-(5-Isopropenyl-2-methyl-cyclopent-1-enyl)-propionic acid ethyl ester 
• 145397-89-3 6-Iodo-9-isopropenyl-6-methyl-1-oxa-spiro[4.4]nonan-2-one 
• 145397-95-1 2-Methyl-6-methylene-11-oxa-tricyclo[7.2.1.0^1,5]dodecan-10-one 
• 145397-93-9 6-Isopropenyl-9-methyl-2-oxo-1-oxa-spiro[4.4]nonane-3-carbaldehyde 
• 145397-90-6 6-Isopropenyl-9-methyl-1-oxa-spiro[4.4]nonan-2-one 
• 29171-20-8 3,7-dimethyloct-6-en-1-yn-3-ol 
• 130722-27-9 (1S,2R,5R,9R)-2,10,10-Trimethyl-6-methylene-11-oxa-tricyclo[7.2.1.0^1,5]dodecane 
• 22451-73-6 2-(3,8-dimethyl-1,2,3,3a,4,5,6,7-octahydro-5-azulenyl)-2-propanol 

Relevant academic research and scientific papers

Revisiting the Chemistry of Guaiacwood Oil: Identification and Formation Pathways of 5,11- and 10,11-Epoxyguaianes

Guaiacwood oil from Bulnesia sarmientoi Lorentz ex. Griseb is a common natural ingredient of the perfume industry used in both domestic and luxury fragrances for its highly appreciated woody-rosy odor, as well as its excellent fixative properties. Despite its long and traditional use as a perfume ingredient, guaiacwood oil has not been extensively studied. Thus, the chemical characterization of its constituents by using a full array of GC-hyphenated techniques (GC-MS, GC × GC-MS, and pc-GC) combined with conventional chemical fractionation was undertaken. In the course of this work, 15 new sesquiterpenoids mostly belonging to the 5,11- and 10,11-epoxyguaiane families were identified. Each isolated compound was fully characterized by NMR and MS. Collectively, the specific chemical relationships observed between sesquiterpene oxides and alcohols permitted the formulation of probable formation pathways regarding their presence as natural constituents of guaiacwood extracts.

Stereoselective Reduction of α-Iodospirolactones. Total Synthesis of (+/-)-Liguloxide.

Radical-mediated reduction of α-methyl-α-iodospirolactones yielded trans-α-methylspirolactones selectively.This reaction was used in the total synthesis of (+/-)-liguloxide.