4-Chloronaphthalene-1,2-diol;diacetate

Base Information

Chemical Name:4-Chloronaphthalene-1,2-diol;diacetate
CAS No.:57396-88-0
Molecular Formula:C₁₄H₁₁ClO₄
Molecular Weight:278.692
Hs Code.:
DSSTox Substance ID:DTXSID60702336
Mol file:57396-88-0.mol

Synonyms:DTXSID60702336;4-chloronaphthalene-1,2-diol;diacetate

Suppliers and Price of 4-Chloronaphthalene-1,2-diol;diacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 4-Chloronaphthalene-1,2-diol;diacetate

Chemical Property:

PSA：120.72000
LogP:3.96260
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:0
Exact Mass:312.0400658
Heavy Atom Count:21
Complexity:211

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)[O-].CC(=O)[O-].C1=CC=C2C(=C1)C(=CC(=C2O)O)Cl

Technology Process of 4-Chloronaphthalene-1,2-diol;diacetate

There total 2 articles about 4-Chloronaphthalene-1,2-diol;diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 139127-53-0
4-chloro-2-diazo-1(2H)-naphthalenone

: 108-24-7
acetic anhydride

: 57396-88-0
C₁₄H₁₁ClO₄

Guidance literature:: 4-chloro-2-diazo-1(2H)-naphthalenone; acetic anhydride; With dirhodium tetraacetate; at 50 ℃; for 4h; Inert atmosphere;

With pyridine; at 50 ℃; Inert atmosphere;
DOI:10.1002/ejoc.201101698

Reference yield:

: 604-44-4
4-chloronaphthalen-1-ol

: 57396-88-0
C₁₄H₁₁ClO₄

Guidance literature:: Multi-step reaction with 2 steps

1.1: 2-azido-1,3-dimethylimidazolinium chloride; triethylamine / Inert atmosphere

2.1: dirhodium tetraacetate / 4 h / 50 °C / Inert atmosphere

2.2: 50 °C / Inert atmosphere

With dirhodium tetraacetate; 2-azido-1,3-dimethylimidazolinium chloride; triethylamine;
DOI:10.1002/ejoc.201101698