3-(1,3-Dioxan-2-yl)benzaldehyde

Base Information

Chemical Name:3-(1,3-Dioxan-2-yl)benzaldehyde
CAS No.:169339-42-8
Molecular Formula:C11H12O3
Molecular Weight:192.214
Hs Code.:2932999099
DSSTox Substance ID:DTXSID60434867
Mol file:169339-42-8.mol

Synonyms:3-(1,3-dioxan-2-yl)benzaldehyde;169339-42-8;MFCD07700184;Benzaldehyde, 3-(1,3-dioxan-2-yl)- (9CI);SCHEMBL6196036;DTXSID60434867;AKOS006287753

Suppliers and Price of 3-(1,3-Dioxan-2-yl)benzaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Rieke Metals
3-(1,3-Dioxan-2-yl)benzaldehyde 97%
1g
$ 383.00

Rieke Metals
3-(1,3-Dioxan-2-yl)benzaldehyde 97%
5g
$ 1850.00

Rieke Metals
3-(1,3-Dioxan-2-yl)benzaldehyde 97%
2g
$ 1309.00

Matrix Scientific
3-(1,3-Dioxan-2-yl)benzaldehyde 97%
1g
$ 385.00

Matrix Scientific
3-(1,3-Dioxan-2-yl)benzaldehyde 97%
5g
$ 1238.00

Matrix Scientific
3-(1,3-Dioxan-2-yl)benzaldehyde 97%
10g
$ 1647.00

Crysdot
3-(1,3-Dioxan-2-yl)benzaldehyde 95+%
10g
$ 1634.00

Crysdot
3-(1,3-Dioxan-2-yl)benzaldehyde 95+%
1g
$ 381.00

Crysdot
3-(1,3-Dioxan-2-yl)benzaldehyde 95+%
5g
$ 1229.00

American Custom Chemicals Corporation
3-(1,3-DIOXAN-2-YL)BENZALDEHYDE 95.00%
10G
$ 2910.60

Total 1 raw suppliers

Chemical Property of 3-(1,3-Dioxan-2-yl)benzaldehyde

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Boiling Point:322.152°C at 760 mmHg
Flash Point:139.669°C
PSA：35.53000
Density:1.169g/cm³
LogP:1.93460
XLogP3:1.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:192.078644241
Heavy Atom Count:14
Complexity:187

Purity/Quality:: 3-(1,3-Dioxan-2-yl)benzaldehyde 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1COC(OC1)C2=CC=CC(=C2)C=O

Technology Process of 3-(1,3-Dioxan-2-yl)benzaldehyde

There total 1 articles about 3-(1,3-Dioxan-2-yl)benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3132-99-8
m-bromobenzoic aldehyde

: 169339-42-8
2-(3-formylphenyl)-1,3-dioxane

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / p-toluenesulfonic acid / toluene / 2.5 h / Heating

2: 1.) n-BuLi / 1.) hexane, THF, from -100 deg C to -78 deg C, 1 h 25 min, 2.) hexane, THF, -70 deg C, 1 h

With n-butyllithium; toluene-4-sulfonic acid; In toluene;
DOI:10.1021/jm00010a005

Reference yield: 93.0%

: 169339-42-8
2-(3-formylphenyl)-1,3-dioxane

: 163164-08-7
2-<3-(hydroxymethyl)phenyl>-1,3-dioxane

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 0 ℃; for 2h;
DOI:10.1021/jm00010a005

Reference yield:

: 169339-42-8
2-(3-formylphenyl)-1,3-dioxane

: (E)-7-(4-{3-[(2R,4R,5S)-5-((Z)-5-Carboxy-pent-2-enyl)-4-(2-hydroxy-phenyl)-[1,3]dioxan-2-yl]-benzyloxy}-phenyl)-7-pyridin-3-yl-hept-6-enoic acid

Guidance literature:: Multi-step reaction with 6 steps

1: 93 percent / LiAlH₄ / diethyl ether / 2 h / 0 °C

2: Ph₃P, diethyl azodicarboxylate / tetrahydrofuran / 16 h

3: 1 M aq. HCl / 0.5 h

4: p-toluenesulfonic acid / CH₂Cl₂ / 2 h / Ambient temperature

5: tetrabutylammonium fluoride / tetrahydrofuran / 1 h / Ambient temperature

6: 1 M aq. NaOH / methanol / 3 h / 25 °C

With hydrogenchloride; sodium hydroxide; lithium aluminium tetrahydride; tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane;
DOI:10.1021/jm00010a005