(3S,4S,5R)-6-(allyloxy)-3,4,5-tris(benzyloxy)-2,2-bis(((4-methoxybenzyl)oxy)methyl)tetrahydro-2H-pyran

Base Information

Chemical Name:(3S,4S,5R)-6-(allyloxy)-3,4,5-tris(benzyloxy)-2,2-bis(((4-methoxybenzyl)oxy)methyl)tetrahydro-2H-pyran
CAS No.:1210344-28-7
Molecular Formula:C47H52O9
Molecular Weight:760.924
Hs Code.:
Mol file:1210344-28-7.mol

Synonyms:(3S,4S,5R)-6-(allyloxy)-3,4,5-tris(benzyloxy)-2,2-bis(((4-methoxybenzyl)oxy)methyl)tetrahydro-2H-pyran

Suppliers and Price of (3S,4S,5R)-6-(allyloxy)-3,4,5-tris(benzyloxy)-2,2-bis(((4-methoxybenzyl)oxy)methyl)tetrahydro-2H-pyran

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4S,5R)-6-(allyloxy)-3,4,5-tris(benzyloxy)-2,2-bis(((4-methoxybenzyl)oxy)methyl)tetrahydro-2H-pyran

Chemical Property:

PSA：83.07000
LogP:8.49110

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

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Useful:

Technology Process of (3S,4S,5R)-6-(allyloxy)-3,4,5-tris(benzyloxy)-2,2-bis(((4-methoxybenzyl)oxy)methyl)tetrahydro-2H-pyran

There total 3 articles about (3S,4S,5R)-6-(allyloxy)-3,4,5-tris(benzyloxy)-2,2-bis(((4-methoxybenzyl)oxy)methyl)tetrahydro-2H-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 1210344-25-4
((3S,4S,5R)-6-allyloxy-3,4,5-tris-benzyloxy-2-hydroxymethyl-tetrahydro-pyran-2-yl)-methanol

: 2746-25-0
p-Methoxybenzyl bromide

: 1210344-28-7
(3S,4S,5R)-6-allyloxy-3,4,5-tris-benzyloxy-2,2-bis(4-methoxybenzyloxymethyl)tetrahydropyrane

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 - 60 ℃;

Reference yield:

: C₃₀H₃₂O₆

: 1210344-28-7
(3S,4S,5R)-6-allyloxy-3,4,5-tris-benzyloxy-2,2-bis(4-methoxybenzyloxymethyl)tetrahydropyrane

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydroxide / water; isopropyl alcohol / 23 °C / Inert atmosphere

2: sodium hydride / N,N-dimethyl-formamide / 0 - 60 °C / Inert atmosphere

With sodium hydride; sodium hydroxide; In water; N,N-dimethyl-formamide; isopropyl alcohol; 1: Aldol condensation;
DOI:10.1021/jm200049r

Reference yield:

: 54606-68-7
((2R,3R,4S,5R)-6-allyloxy-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yl)-methanol

: 1210344-28-7
(3S,4S,5R)-6-allyloxy-3,4,5-tris-benzyloxy-2,2-bis(4-methoxybenzyloxymethyl)tetrahydropyrane

Guidance literature:: Multi-step reaction with 3 steps

1: Inert atmosphere

2: sodium hydroxide / water; isopropyl alcohol / 23 °C / Inert atmosphere

3: sodium hydride / N,N-dimethyl-formamide / 0 - 60 °C / Inert atmosphere

With sodium hydride; sodium hydroxide; In water; N,N-dimethyl-formamide; isopropyl alcohol; 1: Swern oxidation / 2: Aldol condensation;
DOI:10.1021/jm200049r