Carbamic acid, [(1S)-1-methyl-4-pentenyl]-, 1,1-dimethylethyl ester (9CI)

Base Information

• Chemical Name: Carbamic acid, [(1S)-1-methyl-4-pentenyl]-, 1,1-dimethylethyl ester (9CI)
• CAS No.: 363599-41-1
• Molecular Formula: C₁₁H₂₁NO₂
• Molecular Weight: 199.293
• Mol file: 363599-41-1.mol

Synonyms:Carbamic acid, [(1S)-1-methyl-4-pentenyl]-, 1,1-dimethylethyl ester (9CI)

Chemical Property of Carbamic acid, [(1S)-1-methyl-4-pentenyl]-, 1,1-dimethylethyl ester (9CI)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbamic acid, [(1S)-1-methyl-4-pentenyl]-, 1,1-dimethylethyl ester (9CI)

There total 5 articles about Carbamic acid, [(1S)-1-methyl-4-pentenyl]-, 1,1-dimethylethyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-aminohex-5-ene (7380-76-9,73604-43-0) + di-tert-butyl dicarbonate (24424-99-5) → (+/-)-tert-butyl hex-5-en-2-ylcarbamate (169268-97-7,363599-41-1)

Guidance literature:

With triethylamine; In methanol; for 0.5h; Heating;

DOI:10.1080/00397919508015894

Reference yield: 55.0%

allyl bromide (106-95-6) + tert-butyl N-[(1S)-2-iodo-1-methylethyl]carbamate (161529-20-0,446060-78-2) → (2S)-N-(Hex-5-en-2-yl)carbamic acid tert-butyl ester (363599-41-1)

Guidance literature:

tert-butyl N-[(1S)-2-iodo-1-methylethyl]carbamate; With chloro-trimethyl-silane; zinc; In N,N-dimethyl-formamide; at 0 ℃;

allyl bromide; With copper(I) bromide dimethylsulfide complex; In N,N-dimethyl-formamide; at 20 ℃; for 14h; Further stages.;

DOI:10.1039/b102446a

Reference yield:

N-(1-methylpent-4-en-1-yl)(4-methylphenyl)sulfonamide (898832-97-8) + di-tert-butyl dicarbonate (24424-99-5) → (+/-)-tert-butyl hex-5-en-2-ylcarbamate (169268-97-7,363599-41-1)

Guidance literature:

N-(1-methylpent-4-en-1-yl)(4-methylphenyl)sulfonamide; di-tert-butyl dicarbonate; With dmap; triethylamine; at 20 ℃; for 3h;

With magnesium; In methanol; at 20 ℃; for 0.416667h; Sonication;

DOI:10.1016/j.chempr.2021.10.022

upstream raw materials:

2-aminohex-5-ene

di-tert-butyl dicarbonate

N-(hexan-2-yl)-4-methylbenzenesulfonamide

N-(1-methylpent-4-en-1-yl)(4-methylphenyl)sulfonamide