2-(Benzo[d][1,3]dioxol-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

• Chemical Name: 2-(Benzo[d][1,3]dioxol-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS No.: 1073339-10-2
• Molecular Formula: C₁₃H₁₇BO₄
• Molecular Weight: 248.087
• Hs Code.: 2932990090
• Mol file: 1073339-10-2.mol

Synonyms:2-(Benzo[d][1,3]dioxol-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;2,3-Methylenedioxyphenylboronic acid pinacol ester

Chemical Property of 2-(Benzo[d][1,3]dioxol-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

• PSA: 36.92000
• LogP: 1.71450

Purity/Quality:

97% ^*data from raw suppliers

2,3-MethylenedioxyphenylboronicAcidPinacolEster ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(Benzo[d][1,3]dioxol-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 5 articles about 2-(Benzo[d][1,3]dioxol-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.5%

Methylenedioxybenzene (274-09-9) + 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (61676-62-8) → 2-(benzo[d][1,3]dioxol-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1073339-10-2)

Guidance literature:

Methylenedioxybenzene; With sec.-butyllithium; In tetrahydrofuran; cyclohexane; at -108 - -100 ℃; for 2h;

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; In tetrahydrofuran; cyclohexane; at -100 ℃;

Reference yield: 25.0%

Methylenedioxybenzene (274-09-9) + bis(pinacol)diborane (73183-34-3) → 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3-benzodioxole (94838-82-1) + 2-(benzo[d][1,3]dioxol-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1073339-10-2)

Guidance literature:

With (1,5-cyclooctadiene)(methoxy)iridium(l) dimer; 2,2'-bis(2-oxazoline); In cyclohexane; at 70 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c0cc02041a

Reference yield:

Methylenedioxybenzene (274-09-9) + bis(pinacol)diborane (73183-34-3) → 2-(benzo[d][1,3]dioxol-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1073339-10-2)

Guidance literature:

With iridium catalyst; regioselective reaction;

DOI:10.1126/science.1248042

upstream raw materials:

Methylenedioxybenzene

(dippe)Ir(Bpin)3

bis(pinacol)diborane

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1073339-10-2 2-(Benzo[d][1,3]dioxol-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Send

Send

Metric Ton KG G Pound L ML

Send

Send