1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluorohexane

Base Information

• Chemical Name: 1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluorohexane
• CAS No.: 336-07-2
• Molecular Formula: C₆H₂F₁₂
• Molecular Weight: 302.063
• Hs Code.: 29033990
• European Community (EC) Number: 671-790-8
• DSSTox Substance ID: DTXSID5075230
• Nikkaji Number: J672.550C
• Wikidata: Q81985422
• Mol file: 336-07-2.mol

Synonyms:1H,6H-Perfluorohexane;336-07-2;1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluorohexane;alpha,omega-Dihydroperfluorohexane;Hexane, 1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-;1h,6h-dodecafluorohexane;SCHEMBL498059;DTXSID5075230;C6H2F12;MFCD00155777;AKOS016015574;FT-0631978;A821866;J-019268

Chemical Property of 1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluorohexane

Chemical Property:

• Vapor Pressure: 54.6mmHg at 25°C
• Refractive Index: 1.258
• Boiling Point: 94.2 °C at 760 mmHg
• Flash Point: 16.4 °C
• PSA: 0.00000
• Density: 1.557 g/cm³
• LogP: 4.05780
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 5
• Exact Mass: 301.9964880
• Heavy Atom Count: 18
• Complexity: 261

Purity/Quality:

97% ^*data from raw suppliers

1H,6H-Dodecafluorohexane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(C(C(C(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of 1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluorohexane

There total 14 articles about 1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluorohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1-chloro-1H,6H-dodecafluoro-hexane (307-22-2) → 1H,6H-perfluorohexane (336-07-2)

Guidance literature:

With hydrazine hydrate; zinc; In N,N-dimethyl-formamide; at 70 ℃; for 2h;

DOI:10.1016/0022-1139(95)03232-3

Reference yield: 92.0%

1-Chloro-1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-6-iodo-hexane (16486-97-8) → 1H,6H-perfluorohexane (336-07-2)

Guidance literature:

With hydrazine hydrate; zinc; In N,N-dimethyl-formamide; at 80 ℃; for 2h;

DOI:10.1016/0022-1139(95)03232-3

Reference yield: 92.0%

dodecafluoro-1,6-diiodohexane (375-80-4) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → 1H,6H-perfluorohexane (336-07-2) + 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoro-octanedial (148291-67-2) + 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoro-octanedioic acid bis-dimethylamide

Guidance literature:

With lead(II) bromide; aluminium; for 1.5h; Ambient temperature;

DOI:10.1016/S0022-1139(00)80105-0

upstream raw materials:

trichloro-(6H-dodecafluoro-hexyl)-silane

2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptanal

1H,6H-dodecafluoro-1,6-bis-methanesulfonyl-hexane

2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptanoic acid