(S)-CAMPHORSULFONIC ACID DIISOPROPYLAMIDE GLYCOLATE ACETAL

Base Information

Chemical Name:(S)-CAMPHORSULFONIC ACID DIISOPROPYLAMIDE GLYCOLATE ACETAL
CAS No.:163182-10-3
Molecular Formula:C18H31NO5S
Molecular Weight:373.51
Hs Code.:
Mol file:163182-10-3.mol

Synonyms:(S)-CAMPHORSULFONIC ACID DIISOPROPYLAMIDE GLYCOLATE ACETAL;[1S-(1ALPHA,2ALPHA,4BETA)]-N,N-DIISOPROPYL-7,7-DIMETHYL-4'-OXOSPIRO[BICYCLO[2.2.1]HEPTANE-2,2'-[1,3]DIOXOLANE]-1-METHANESULFONAMIDE

Suppliers and Price of (S)-CAMPHORSULFONIC ACID DIISOPROPYLAMIDE GLYCOLATE ACETAL

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
(S)-(-)-CAMPHORSULFONIC ACID DIISOPROPYLAMIDE GLYCOLATE ACETAL 95.00%
5MG
$ 501.60

Total 2 raw suppliers

Chemical Property of (S)-CAMPHORSULFONIC ACID DIISOPROPYLAMIDE GLYCOLATE ACETAL

Chemical Property:

PSA：81.29000
LogP:3.61180

Purity/Quality:

99% ^*data from raw suppliers

(S)-(-)-CAMPHORSULFONIC ACID DIISOPROPYLAMIDE GLYCOLATE ACETAL 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (S)-CAMPHORSULFONIC ACID DIISOPROPYLAMIDE GLYCOLATE ACETAL

There total 4 articles about (S)-CAMPHORSULFONIC ACID DIISOPROPYLAMIDE GLYCOLATE ACETAL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 256393-05-2
(1S)-N,N-diisopropyl (2,2-dimethoxy-7,7-dimethylbicyclo[2.2.1]hept-1-yl)methanesulfonamide

: 79-14-1
glycolic Acid

: 163182-10-3
(1S,2S)-N,N-diisopropyl [2-spiro-2'-(1',3'-dioxolane-4'-one)-7,7-dimethylbicyclo[2.2.1]hept-1-yl]methanesulfonamide

Guidance literature:: With boron trifluoride diethyl etherate; In diethyl ether; dichloromethane; at -50 ℃; for 0.666667 - 1.16667h;

Reference yield: 74.0%

: 256393-05-2
(1S)-N,N-diisopropyl (2,2-dimethoxy-7,7-dimethylbicyclo[2.2.1]hept-1-yl)methanesulfonamide

: 79-14-1
glycolic Acid

: (1S,2R)-N,N-diisopropyl [2-spiro-2'-(1',3'-dioxolane-4'-one)-7,7-dimethylbicyclo[2.2.1]hept-1-yl]methanesulfonamide

: 163182-10-3
(1S,2S)-N,N-diisopropyl [2-spiro-2'-(1',3'-dioxolane-4'-one)-7,7-dimethylbicyclo[2.2.1]hept-1-yl]methanesulfonamide

Guidance literature:: With boron trifluoride diethyl etherate; In diethyl ether; at -50 - -45 ℃;
DOI:10.1021/ol9910666

Reference yield:

: 256393-09-6
(1S,2S,5'R)-N,N-diisopropyl [2-spiro-2'-(5'-phenylmethyl-1',3'-dioxolane-4'-one)-7,7-dimethylbicyclo[2.2.1]hept-1-yl]methanesulfonamide

: 163182-10-3
(1S,2S)-N,N-diisopropyl [2-spiro-2'-(1',3'-dioxolane-4'-one)-7,7-dimethylbicyclo[2.2.1]hept-1-yl]methanesulfonamide

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / hydrogen chloride / 6 h / Heating

2: 85 percent / PTSA / 84 h / 20 °C

3: 74 percent / BF₃*OEt₂ / diethyl ether / -50 - -45 °C

With hydrogenchloride; boron trifluoride diethyl etherate; toluene-4-sulfonic acid; In diethyl ether;
DOI:10.1021/ol9910666