(Z)-1,4-Undecadiene

Base Information

• Chemical Name: (Z)-1,4-Undecadiene
• CAS No.: 55976-14-2
• Molecular Formula: C8H9ClS2
• Molecular Weight: 152.28
• Mol file: 55976-14-2.mol

Synonyms:(Z)-1,4-Undecadiene

Chemical Property of (Z)-1,4-Undecadiene

Chemical Property:

• PSA: 50.60000
• LogP: 4.10020

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (Z)-1,4-Undecadiene

There total 6 articles about (Z)-1,4-Undecadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

undeca-1-en-4-yne (31508-11-9) → (Z)-1,4-undecadiene (55976-14-2)

Guidance literature:

With quinoline; hydrogen; Lindlar catalyst; In Petroleum ether;

DOI:10.1002/hlca.19800630832

Reference yield: 39.0%

ethene (74-85-1) + (E)-1,3-nonadiene (77192-27-9) → (Z)-4-vinylnon-2-ene (1215227-10-3) + (Z)-1,4-undecadiene (55976-14-2)

Guidance literature:

With C₁₆H₃₂Cl₂CoP₂; trimethylaluminum; In toluene; at -10 ℃; for 8h; under 760.051 Torr; enantioselective reaction;

DOI:10.1039/c5sc00929d

Reference yield:

ethene (74-85-1) + (E)-1,3-nonadiene (77192-27-9) → (Z)-4-vinylnon-2-ene (1215227-04-5) + (Z)-1,4-undecadiene (55976-14-2)

Guidance literature:

With {Co(P(C₆H₅)2(CH₂)4P(C₆H₅)2)Br₂}; trimethylaluminum; In dichloromethane; at -20 ℃; for 20h; under 760.051 Torr; Reagent/catalyst; regioselective reaction;

DOI:10.1039/c5sc00929d

upstream raw materials:

undeca-1-en-4-yne

[(1S,2R)-2-((R)-1-Trimethylsilanyl-heptyl)-cyclopropyl]-methanol

n-octyne

ethene

Downstream raw materials:

(2Z,4E)-undeca-2,4-dien-1-ol

Refernces

• 1、 Wilson, Stephen R.,Zucker, Paul A.. "Silicon-Mediated Skipped Diene Synthesis. Application to the Melon Fly Pheromone". . p. 4682 - 4693. Retrieved 2007/10/02.