Lithium;azanide;boron

Base Information

• Chemical Name: Lithium;azanide;boron
• CAS No.: 99144-67-9
• Molecular Formula: BH₅N*Li
• Molecular Weight: 36.7984
• European Community (EC) Number: 693-026-2
• DSSTox Substance ID: DTXSID70453281
• Mol file: 99144-67-9.mol

Synonyms:lithium;azanide;boron;99144-67-9;CID 11051563;Borate(1-), amidotrihydro-, lithium, (T-4)-;DTXSID70453281;Lithium ammonia borane, technical grade

Chemical Property of Lithium;azanide;boron

Chemical Property:

• PSA: 26.02000
• LogP: -0.46680
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 34.0440327
• Heavy Atom Count: 3
• Complexity: 2

Purity/Quality:

98%,99%, ^*data from raw suppliers

Lithium ammonia borane technical grade ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,C
• Statements: 14/15-34
• Safety Statements: 26-36/37/39-43-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Li+].[B].[NH2-]
• Uses: Base material for alternative energy applications.1 This boron-based hydride is a low temperature source of hydrogen for fuel cells and other hydrogen consuming energy systems. Can also serve as an excellent reducing agent in various chemical processes.2 Lithium ammonia borane (LiNH2BH3) is an alkali-metal amidoborane that is mainly used in hydrogen storage applications. It has a hydrogen release percentage of ~10.9% at a low temperature (~90°C).

Technology Process of Lithium;azanide;boron

There total 1 articles about Lithium;azanide;boron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

borane-ammonia complex (10043-11-5) + lithium hydride → 2Li(1+)*NHBH3(2-)=Li2NHBH3 + lithium amidoborane (99144-67-9)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2; LiH and NH3BH3 in a molar ratio of 1:1 were mech. milled under 1 bar of Ar at 200 rpm on a planetary mill; detd. by XRD;

DOI:10.1021/ic100308j

upstream raw materials:

borane-ammonia complex

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