Tert-butyldimethyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)silane

Base Information

Chemical Name:Tert-butyldimethyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)silane
CAS No.:902120-00-7
Molecular Formula:C18H31BO3Si
Molecular Weight:334.33344
Hs Code.:2931900090
DSSTox Substance ID:DTXSID00468348
Nikkaji Number:J2.352.078H
Wikidata:Q82295521
Mol file:902120-00-7.mol

Synonyms:902120-00-7;tert-butyldimethyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)silane;3-(t-Butyldimethylsilyloxy)phenylboronic acid, pinacol ester;tert-butyl-dimethyl-[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy]silane;AGN-PC-00B9WU;3-(t-Butyldimethylsilyloxy)phenylboronic acid,pinacol ester;DTXSID00468348;MFCD04039307;AKOS025287026;BS-29709;CS-0176678;E89734;EN300-1425738;tert-butyldimethyl[3-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy]silane

Suppliers and Price of Tert-butyldimethyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
3-(t-Butyldimethylsilyloxy)phenylboronicacid,pinacolester
1g
$ 220.00

Crysdot
tert-butyldimethyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)silane 95+%
5g
$ 376.00

AOBChem
3-(T-BUTYLDIMETHYLSILYLOXY)PHENYLBORONICACID,PINACOLESTER 97%
10g
$ 736.00

AK Scientific
3-(t-Butyldimethylsilyloxy)phenylboronicacidpinacolester
5g
$ 584.00

Total 8 raw suppliers

Chemical Property of Tert-butyldimethyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)silane

Chemical Property:

PSA：27.69000
LogP:4.36980
Storage Temp.:Refrigerated.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:334.2135515
Heavy Atom Count:23
Complexity:413

Purity/Quality:

95% ^*data from raw suppliers

3-(t-Butyldimethylsilyloxy)phenylboronicacid,pinacolester ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=CC(=CC=C2)O[Si](C)(C)C(C)(C)C

Technology Process of Tert-butyldimethyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)silane

There total 1 articles about Tert-butyldimethyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 214360-76-6
3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol

: 902120-00-7
4,4,5,5-tetramethyl-2-(3-tert-butyldimethylsilyloxyphenyl)-1,3-dioxaborolane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 12h;
DOI:10.1039/b603857c

Reference yield: 65.0%

: 902119-99-7
di(isopropyl)carbamic acid 3-(3,4,5-trimethoxyphenyl)propyl ester

: 902120-00-7
4,4,5,5-tetramethyl-2-(3-tert-butyldimethylsilyloxyphenyl)-1,3-dioxaborolane

: 902119-94-2
(R)-(+)-1-[3-(tert-butyldimethylsilyloxy)phenyl]-3-(3,4,5-trimethoxyphenyl)propan-1-ol

Guidance literature:: Multistep reaction.;
DOI:10.1039/b603857c

Reference yield: 40.0%

: 902120-00-7
4,4,5,5-tetramethyl-2-(3-tert-butyldimethylsilyloxyphenyl)-1,3-dioxaborolane

: 1663-39-4,25232-27-3
tert-Butyl acrylate

: 2969-81-5
Ethyl 4-bromobutyrate

: diethyl 4,4'-(2-(3-(tert-butoxy)-3-oxoprop-1-en-1-yl)-4-hydroxy-1,3-phenylene)(E)-dibutyrate

Guidance literature:: With 5-norbornene-2-carbonitrile; palladium diacetate; potassium carbonate; In N,N-dimethyl acetamide; at 30 ℃; for 16h; chemoselective reaction; Schlenk technique;
DOI:10.1002/anie.201803865