1-HEXYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

Base Information

• Chemical Name: 1-HEXYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE
• CAS No.: 380497-19-8
• Molecular Formula: C₂F₆NO₄S₂*C₁₁H₂₄N
• Molecular Weight: 450.467
• Mol file: 380497-19-8.mol

Synonyms:1-HEXYL-METHYLPYRROLIDINIUM BIS (TRIFLUOROMETHYLSULFONYL)IMIDE;1-HEXYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

Chemical Property of 1-HEXYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

Chemical Property:

• Melting Point: 5 °C
• PSA: 85.04000
• Density: 1.46 g/cm3
• LogP: 6.23400

Purity/Quality:

99% ^*data from raw suppliers

1-HEXYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-HEXYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

There total 5 articles about 1-HEXYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

N-(n-hexyl)-N-methylpyrrolidinium chloride + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → 1-hexyl-1-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide (380497-19-8)

Guidance literature:

In water; at 20 ℃; for 24h;

DOI:10.1002/cphc.201300098

Reference yield:

bis(trifluoromethane)sulfonimide lithium (90076-65-6) + 1-hexyl-1-methylpyrrolidin-1-ium bromide → 1-hexyl-1-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide (380497-19-8)

Guidance literature:

In water;

DOI:10.1002/cssc.201701006

Reference yield:

1-Methylpyrrolidine (120-94-5) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → 1-hexyl-1-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide (380497-19-8)

Guidance literature:

1-Methylpyrrolidine; 1-hexylhalide; for 12h; Reflux;

bis(trifluoromethane)sulfonimide lithium; In water; for 12h; Inert atmosphere;

DOI:10.1021/jo301348k

upstream raw materials:

1-Methylpyrrolidine

bis(trifluoromethane)sulfonimide lithium

1-Chlorohexane

1-bromo-hexane

Refernces

• 1、 Shirota, Hideaki,Ando, Masatoshi,Kakinuma, Shohei,Takahashi, Kotaro. "Ultrafast dynamics in nonaromatic cation based ionic liquids: A femtosecond raman-induced kerr effect spectroscopic study". . p. 1520 - 1539. Retrieved 2020.
• 2、 Sultana, Sharmin,Tachikawa, Naoki,Yoshii, Kazuki,Toshima, Kazunobu,Magagnin, Luca,Katayama, Yasushi. "Electrochemical Preparation of Platinum Nanoparticles from Bis(acetylacetonato)platinum(II) in Some Aprotic Amide-type Ionic Liquids". . p. 263 - 270. Retrieved 2017/08/29.