dichloroplatinum(2+) 4-cyanopiperidin-1-ide 4-cyano-2H-pyridin-1-ide (1:1:1)

Base Information

• Chemical Name: dichloroplatinum(2+) 4-cyanopiperidin-1-ide 4-cyano-2H-pyridin-1-ide (1:1:1)
• CAS No.: 14282-15-6
• Molecular Formula: C12H14Cl2N4Pt
• Molecular Weight: 480.2564
• Mol file: 14282-15-6.mol

Synonyms:

Chemical Property of dichloroplatinum(2+) 4-cyanopiperidin-1-ide 4-cyano-2H-pyridin-1-ide (1:1:1)

Chemical Property:

• Vapor Pressure: 0.082mmHg at 25°C
• Boiling Point: 226.4°Cat760mmHg
• Flash Point: 90.7°C
• Density: g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dichloroplatinum(2+) 4-cyanopiperidin-1-ide 4-cyano-2H-pyridin-1-ide (1:1:1)

There total 3 articles about dichloroplatinum(2+) 4-cyanopiperidin-1-ide 4-cyano-2H-pyridin-1-ide (1:1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

pyridine-4-carbonitrile (100-48-1) + dichlorobis(dimethyl sulfoxide)platinum(II) → trans-[PtII(4-CNpy)2Cl2] (14282-15-6,24476-73-1)

Guidance literature:

In acetonitrile; at 81.2 ℃;

DOI:10.1021/acs.inorgchem.7b01294

Reference yield:

pyridine-4-carbonitrile (100-48-1) + potassium tetrachloroplatinate(II) (10025-99-7) → cis-{Pt(4-CN-py)2Cl2} (24476-73-1,14282-15-6)

Guidance literature:

In water; dissoln. of 2.64 mmol of 4-cyanopyridine in a minimum amount of water; addn. to a stirred soln. of 1.205 mmol K2(PtCl4) in distilled water; stirring for several hours; storing in a refrigerator; pptn.; filtration;; washing twice with ice-water, ice-ethanol and ether; drying in vac. over P2O5; elem. anal.;;

DOI:10.1039/DT9930000233

Reference yield:

pyridine-4-carbonitrile (100-48-1) + potassium tetrachloroplatinate(II) (10025-99-7) → trans-[PtII(4-CNpy)2Cl2] (14282-15-6,24476-73-1)

Guidance literature:

In N,N-dimethyl-formamide; addn. of 2.1 molar equivalents of 4-cyanopyridine to a soln. of K2(PtCl4) in DMF; keeping at 80°C for 6 h; evaporation of the solvent under reduced pressure;; crystallization of the residue from boiling chloroform; elem. anal.;;

DOI:10.1039/DT9930000233

upstream raw materials:

pyridine-4-carbonitrile

potassium tetrachloroplatinate(II)

Refernces

• 1、 Cattalini, Lucio,Guidi, Francesca,Tobe, Martin L.. "The cis- and trans-Effects of Cyanide in Substitution at Platinum(II)". . p. 233 - 236. Retrieved 2007/10/02.