Ethyl 2-[4-(4,4,5,5-TetraMethyl-1,3,2-dioxaborolan-2-yl)phenyl]propanoate

Base Information

Chemical Name:Ethyl 2-[4-(4,4,5,5-TetraMethyl-1,3,2-dioxaborolan-2-yl)phenyl]propanoate
CAS No.:1228690-28-5
Molecular Formula:C17H25BO4
Molecular Weight:304.194
Hs Code.:

Synonyms:Ethyl 2-[4-(4,4,5,5-TetraMethyl-1,3,2-dioxaborolan-2-yl)phenyl]propanoate

Suppliers and Price of Ethyl 2-[4-(4,4,5,5-TetraMethyl-1,3,2-dioxaborolan-2-yl)phenyl]propanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 3 raw suppliers

Chemical Property of Ethyl 2-[4-(4,4,5,5-TetraMethyl-1,3,2-dioxaborolan-2-yl)phenyl]propanoate

Chemical Property:

Purity/Quality:: 98%+ ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Ethyl 2-[4-(4,4,5,5-TetraMethyl-1,3,2-dioxaborolan-2-yl)phenyl]propanoate

There total 5 articles about Ethyl 2-[4-(4,4,5,5-TetraMethyl-1,3,2-dioxaborolan-2-yl)phenyl]propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 111914-79-5
(+/-)-2-(4-bromophenyl)propionic acid ethyl ester

: 73183-34-3
bis(pinacol)diborane

: 1228690-28-5
(±)-ethyl 2-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)propanoate

Guidance literature:: With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium acetate; In 1,4-dioxane; at 110 ℃; for 16h; Inert atmosphere; Sealed tube;

Reference yield: 58.0%

: 535-13-7
2-chloro-propanoic acid, ethyl ester

: 68716-49-4
p-bromophenylboronic acid pinacol ester

: 1228690-28-5
(±)-ethyl 2-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)propanoate

Guidance literature:: With 2,6-dimethylpyridine; (1,2-dimethoxyethane)dichloronickel(II); tris(triethylsilyl)silane; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate; 4,4'-di-tert-butyl-2,2'-bipyridine; In 1,2-dimethoxyethane; at 25 ℃; for 8h; Inert atmosphere; Sealed tube; Irradiation;
DOI:10.1002/anie.201909072

Reference yield:

: 111914-79-5
(+/-)-2-(4-bromophenyl)propionic acid ethyl ester

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1228690-28-5
(±)-ethyl 2-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)propanoate

Guidance literature:: With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; triethylamine; dichloro bis(acetonitrile) palladium(II); In 1,4-dioxane; at 110 ℃; for 4h; Inert atmosphere;