2,6-ANHYDRO-1-DEOXY-1-NITRO-3,4,5-TRI-O-ACETYL-D-GULITOL

Base Information

• Chemical Name: 2,6-ANHYDRO-1-DEOXY-1-NITRO-3,4,5-TRI-O-ACETYL-D-GULITOL
• CAS No.: 20204-84-6
• Molecular Formula: C₆H₁₁NO₆
• Molecular Weight: 193.156
• Hs Code.: 2932999099
• Mol file: 20204-84-6.mol

Synonyms:BETA-D-XYLOPYRANOSYL NITROMETHANE;2,6-ANHYDRO-1-DEOXY-1-NITRO-3,4,5-TRI-O-ACETYL-D-GULITOL;SS-D-XYLOPYRANOSYL NITROMETHANE,2,6-ANHYDRO-1-DEOXY-1-NITRO-3,4,5-TRI-O-ACETYL-D-GULITOL

Chemical Property of 2,6-ANHYDRO-1-DEOXY-1-NITRO-3,4,5-TRI-O-ACETYL-D-GULITOL

Chemical Property:

• PSA: 115.74000
• LogP: -1.73220

Purity/Quality:

99%min ^*data from raw suppliers

2,6-ANHYDRO-1-DEOXY-1-NITRO-3,4,5-TRI-O-ACETYL-D-GULITOL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,6-ANHYDRO-1-DEOXY-1-NITRO-3,4,5-TRI-O-ACETYL-D-GULITOL

There total 3 articles about 2,6-ANHYDRO-1-DEOXY-1-NITRO-3,4,5-TRI-O-ACETYL-D-GULITOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nitromethane (75-52-5) + D-ribose (50-69-1) → 2,5-Anhydro-1-desoxy-1-nitro-D-allitol (79733-40-7) + 2,5-Anhydro-1-desoxy-1-nitro-D-altritol (79698-06-9) + (3R,4R,5R)-2-Nitromethyl-tetrahydro-pyran-3,4,5-triol (20204-84-6,70003-99-5,74183-69-0,112571-45-6,113972-91-1)

Guidance literature:

Yield given. Multistep reaction;

DOI:10.1016/0008-6215(87)80143-X

Reference yield:

D-xylose (58-86-6) + nitromethane (75-52-5) → (β-D-Xylopyranosyl)nitromethane (20204-84-6)

Guidance literature:

Yield given. Multistep reaction;

DOI:10.1016/0008-6215(87)80143-X

Reference yield:

→ (β-D-Xylopyranosyl)nitromethane (20204-84-6)

Guidance literature:

DOI:10.1021/jo01065a069

upstream raw materials:

D-xylose

nitromethane

D-ribose

Downstream raw materials:

1,5-anhydro-L-glucitol

Ethyl 2-(diphenylmethyleneamino)-4-nitro-4-(2,3,4-tri-O-acetyl-β-D-xylopyranosyl)butanoate

Ethyl 2-(diphenylmethyleneamino)-4-(2,3,4-tri-O-acetyl-β-D-xylopyranosyl)butanoate

Refernces

• 1、 Foertsch, Armin,Kogelberg, Heide,Koell, Peter. "STEREOCHEMISCHE ASPEKTE IN ZUSAMMENHANG MIT DER SYNTHESE VON 2,6-ANHYDRO-1-DESOXY-1-NITROALDITOLEN". . p. 391 - 402. Retrieved 2007/10/02.