2-PHENYLPROPIONALDEHYDE

Base Information

• Chemical Name: 2-PHENYLPROPIONALDEHYDE
• CAS No.: 34713-70-7
• Molecular Formula: C9H10O
• Molecular Weight: 134.178
• Hs Code.: 2912299000
• Mol file: 34713-70-7.mol

Synonyms:2-PHENYLPROPANAL;2-PHENYLPROPIONALDEHYDE;2-PHENYLPROPANOL;ALPHA-PHENYLPROPIONALDEHYDE;A-METHYL-A-TOLUIC ALDEHYDE;A-METHYLPHENYLACETALDEHYDE;METHYLPHENYLACETALDEHYDE;HYDRATROPIC ALDEHYDE

Chemical Property of 2-PHENYLPROPIONALDEHYDE

Chemical Property:

• Vapor Pressure: 0.294mmHg at 25°C
• Melting Point: -60 °C
• Refractive Index: n20/D 1.517(lit.)
• Boiling Point: 92-94 °C12 mm Hg(lit.)
• Flash Point: 169 °F
• PSA: 17.07000
• Density: 1.002 g/mL at 25 °C(lit.)
• LogP: 1.98900

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-PHENYLPROPIONALDEHYDE

There total 245 articles about 2-PHENYLPROPIONALDEHYDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + carbon monoxide (201230-82-2) → 3-phenyl-propionaldehyde (104-53-0) + ethylbenzene (100-41-4,27536-89-6) + 2-Phenylpropanal (34713-70-7)

Guidance literature:

With hydrogen; RhPtuPF₆; In toluene; at 80 ℃; under 45600 Torr; Further Variations:; Catalysts; Product distribution;

DOI:10.1016/S0022-328X(99)00615-4

Reference yield: 53.0%

hydratropic acid (492-37-5,2328-24-7) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 2-Phenylpropanal (34713-70-7)

Guidance literature:

With hydrogen; 2,2-dimethylpropanoic anhydride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 80 ℃; for 24h; under 22501.8 Torr;

DOI:10.1246/bcsj.74.1803

Reference yield: 46.0%

1-phenylpropylene oxide (4436-22-0) → ethylbenzene (100-41-4,27536-89-6) + 2-Phenylpropanal (34713-70-7) + 1,1'-(1,2-ethanediyl)bisbenzene (103-29-7) + 1-phenyl-acetone (103-79-7,136675-26-8)

Guidance literature:

at 600 ℃;

DOI:10.1007/BF00696928

upstream raw materials:

styrene

2-methyl-2-phenyloxirane

fraeseol

Isopropylbenzene

Downstream raw materials:

2-phenyl-3-heptanone

3-hydroxy-2,2-dimethyl-4-phenyl-valeric acid ethyl ester

3-hydroxy-2,2-dimethyl-4-phenylpentanoate

(E)-2-Phenylprop-1-en-1-yl acetate

Refernces

• 1、 Araghi, Mehdi,Ghorbani, Azam,Yeganeh, Faten Eshrati. "Efficient oxidation of alcohols with tert-butyl hydroperoxide catalyzed by Mo(CO)6 supported on multiwall carbon nanotubes". . p. 109 - 113. Retrieved 2013.
• 2、 Ruiz, Nuria,Aaliti, Abdellatif,Fornies-Camer, Jorge,Ruiz, Aurora,Claver, Carmen,Cardin, Christine J.,Fabbri, Davide,Gladiali, Serafino. "Metal complexes with atropisomeric sulfur ligands in asymmetric hydroformylation: X-ray structure of [Rh2( μ-biphes) ( cod) 2] (H2biphes = 4,4′-biphenanthrene-3,3′-dithiol)". . p. 79 - 87. Retrieved 1997.
• 3、 Srirambalaji, Renganathan,Hong, Soonsang,Natarajan, Ramalingam,Yoon, Minyoung,Hota, Raghunandan,Kim, Yonghwi,Ho Ko, Young,Kim, Kimoon. "Tandem catalysis with a bifunctional site-isolated Lewis acid-Bronsted base metal-organic framework, NH2-MIL-101(Al)". . p. 11650 - 11652. Retrieved 2012.
• 4、 Gao, Peng,Ke, Miaolin,Ru, Tong,Liang, Guanfeng,Chen, Fen-Er. "Synthesis of rac-ɑ-aryl propionaldehydes via branched-selective hydroformylation of terminal arylalkenes using water-soluble Rh-PNP catalyst". . p. 830 - 834. Retrieved 2021/08/26.
• 5、 Paganelli, Stefano,Tassini, Riccardo,Rathod, Vikas D.,Onida, Barbara,Fiorilli, Sonia,Piccolo, Oreste. "A Low Rhodium Content Smart Catalyst for Hydrogenation and Hydroformylation Reactions". . p. 1508 - 1521. Retrieved 2020/10/15.