Diazene, bicyclo[2.2.1]hept-1-yl(1,1-dimethylethyl)-, (Z)- (9CI)

Base Information

• Chemical Name: Diazene, bicyclo[2.2.1]hept-1-yl(1,1-dimethylethyl)-, (Z)- (9CI)
• CAS No.: 126112-72-9
• Molecular Formula: C₁₁H₂₀N₂
• Molecular Weight: 180.293
• Mol file: 126112-72-9.mol

Synonyms:Diazene, bicyclo[2.2.1]hept-1-yl(1,1-dimethylethyl)-, (Z)- (9CI)

Chemical Property of Diazene, bicyclo[2.2.1]hept-1-yl(1,1-dimethylethyl)-, (Z)- (9CI)

Chemical Property:

• PSA: 24.72000
• LogP: 3.56980

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Diazene, bicyclo[2.2.1]hept-1-yl(1,1-dimethylethyl)-, (Z)- (9CI)

There total 6 articles about Diazene, bicyclo[2.2.1]hept-1-yl(1,1-dimethylethyl)-, (Z)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

norbornane-1-carboxylic acid (18720-30-4) → cis-N-tert-Butyl-N'-1-norbornyldiazene (126112-72-9)

Guidance literature:

Multi-step reaction with 5 steps

1: conc. sulfuric acid, sodium azide / CHCl₃

3: 1.) tert-butyl hypochlorite, 2.) potassium tert-butoxide / solvent tert-butyl alcohol

4: 62 percent / 1 N hydrochloric acid

5: Irradiation

With hydrogenchloride; sodium azide; tert-butylhypochlorite; sulfuric acid; potassium tert-butylate; In chloroform;

DOI:10.1021/jo00296a026

Reference yield:

exo,endo-2-bromobicyclo<2.2.1>heptane-1-carboxylic acid (74830-47-0) → cis-N-tert-Butyl-N'-1-norbornyldiazene (126112-72-9)

Guidance literature:

Multi-step reaction with 6 steps

1: 61 percent / tri-n-butyltin hydride

2: conc. sulfuric acid, sodium azide / CHCl₃

4: 1.) tert-butyl hypochlorite, 2.) potassium tert-butoxide / solvent tert-butyl alcohol

5: 62 percent / 1 N hydrochloric acid

6: Irradiation

With hydrogenchloride; sodium azide; tert-butylhypochlorite; sulfuric acid; potassium tert-butylate; tri-n-butyl-tin hydride; In chloroform;

DOI:10.1021/jo00296a026

Reference yield:

N-tert-Butyl-N'-1-norbornylurea (67064-32-8) → cis-N-tert-Butyl-N'-1-norbornyldiazene (126112-72-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 1.) tert-butyl hypochlorite, 2.) potassium tert-butoxide / solvent tert-butyl alcohol

2: 62 percent / 1 N hydrochloric acid

3: Irradiation

With hydrogenchloride; tert-butylhypochlorite; potassium tert-butylate;

DOI:10.1021/jo00296a026

upstream raw materials:

trans-N-tert-Butyl-N'-1-norbornyldiazene

norbornane-1-carboxylic acid

N-tert-Butyl-N'-1-norbornylurea

1-norbornylamine

Downstream raw materials:

trans-N-tert-Butyl-N'-1-norbornyldiazene