Sn(IV) Octaethylporphine dichloride

Base Information

• Chemical Name: Sn(IV) Octaethylporphine dichloride
• CAS No.: 25777-43-9
• Molecular Formula: C36H44Cl2N4Sn
• Molecular Weight: 732.45676
• Mol file: 25777-43-9.mol

Synonyms:Sn(IV) Octaethylporphine dichloride;(Sn(IV)[OEP]Cl2)

Chemical Property of Sn(IV) Octaethylporphine dichloride

Chemical Property:

• PSA: 50.50000
• LogP: -0.55200

Purity/Quality:

98.5% ^*data from raw suppliers

Phthalate Ionophore I ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Phthalate Ionophore I is an ionophore used in phthalate-selective electrodes.

Technology Process of Sn(IV) Octaethylporphine dichloride

There total 2 articles about Sn(IV) Octaethylporphine dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

2,3,7,8,12,13,17,18-octaethylporphyrin (106117-28-6,991-75-3) + tin(II) chloride dihdyrate (10025-69-1) → dichloro(2,3,7,8,12,13,17,18-octaethylporphyrinato)tin(IV) (25777-43-9)

Guidance literature:

In pyridine; refluxing mixt. of tin compd. and porphyrin deriv. in pyridine at 115°C for 2 h; evapn., extn. (CHCl3), washing with aq. HCl, drying with Na2SO4, evapn.,recrystn. (CHCl3/cyclohexane), elem. anal.;

DOI:10.1021/ic901401t

Reference yield:

2,3,7,8,12,13,17,18-octaethyl-porphyrin (2683-82-1,106117-28-6,991-75-3) → dichloro(2,3,7,8,12,13,17,18-octaethylporphyrinato)tin(IV) (25777-43-9)

Guidance literature:

With tin(ll) chloride; In ethanol; chloroform; for 12h; Reflux;

DOI:10.1142/S1088424610002124

upstream raw materials:

2,3,7,8,12,13,17,18-octaethylporphyrin

tin(II) chloride dihdyrate

2,3,7,8,12,13,17,18-octaethyl-porphyrin